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Journal of Structural Chemistry

, Volume 59, Issue 3, pp 744–747 | Cite as

Structural Characterization of a Cu(I)/Br Complex with Bis(4-(1H-Imidazol-1-Yl)Phenyl)Methanone Ligands

  • S.-W. Sun
  • G.-F. Wang
Article
  • 11 Downloads

Abstract

The synthesis of a novel Cu(I) complex with V-shaped bidentate ligands {[Cu(BIPMO)]×[CuBr2]}n where BIPMO = bis(4-(1H-imidazol-1-yl)phenyl)methanone is reported. It is characterized by IR spectroscopy, elemental analysis, and single crystal X-ray diffraction. Copper(I) ions in the complex are in a distorted environment in which donor atoms are provided by the bromide anion and nitrogen atoms of BIPMO ligands, respectively. Infinite anion chains formed by CuX4 (X = Br or N) polyhedra are linked by BIPMO ligands to give rise to layers. Furthermore, the layers are linked into 3D networks through weak intermolecular interactions.

Keywords

synthesis copper complex bidentate ligand crystal structure semirigid ligand imidazole 

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  1. 1.Department of Applied ChemistryYuncheng UniversityYunchengP. R. China

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