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Journal of Structural Chemistry

, Volume 59, Issue 3, pp 729–732 | Cite as

Crystal Structure and Thermal Properties of a 2D Silver(I) Coordination Polymer with Semi-Rigid Bis(Pyrazole)

  • J. Cheng
  • G.-H. Wang
  • Y.-W. Wang
Article
  • 16 Downloads

Abstract

An Ag(I) coordination polymer [Ag2(L)2(H2btc)]n (L = 4,4′-bis(3,5-dimethylpyrazol-1-ylmethyl)-biphenyl, H4btc = 1,2,4,5-benzenetetracarboxylic acid) is hydrothermally synthesized and characterized by elemental analyses, IR spectroscopy, TGA analysis, and single crystal X-ray diffraction. It crystallizes in the triclinic space group Pī, a = 10.670(8) Å, b = 10.990(8) Å, c = 23.697(2) Å, α = 81.847(10), β = 82.171(10), γ = 80.592(10)°, V = 2695.5(3) Å3, Z = 2, Dcalc = 1.489 g/cm3, μ = 0.789 mm–1. The title compound displays a uninodal three-connected hcb/Shubnikov hexagonal plane with {63} topology, which is further extended into a 3D supramolecular framework via C–H···O interactions.

Keywords

Ag(I) complex bis(pyrazole) crystal structure 

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  1. 1.Journal Editorial DepartmentHebei University of Environmental EngineeringQinhuangdao, Hebei ProvinceP. R. China

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