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Journal of Structural Chemistry

, Volume 59, Issue 3, pp 720–724 | Cite as

Structure and Fluorescence Properties of a Two-Dimensional Zinc(II) Coordination Polymer Containing Isophthalate

  • S. Y. Hao
  • Z. C. Hao
  • Y. G. Liu
  • G. Y. Dong
Article

Abstract

A new coordination polymer formulated as [Zn(L)(1,3-BDC)] (L = 1,3-bis-(benzimidazole-1-ylmethylene)-benzene, 1,3-H2BDC = isophthalic acid) is hydrothermally synthesized and characterized by elemental analysis, IR, and single crystal X-ray diffraction analysis. It crystallizes in the monoclinic space group P21/n, a = 10.179(3) Å, b = 10.510(3) Å, c = 23.217(6) Å, α = 90, β = 91.983(3), γ = 90°, V = 2482.4(11) Å3, Z = 4, C30H22N4O4Zn, Mr = 567.91, Dc = 1.520 g/cm3, μ = 1.036 mm–1. The complex exhibits a 2D (4,4) network with the point symbol {44,62} and further extended into a 3D supramolecular framework through π⋯π stacking interactions between two well-overlapping benzimidazolyl rings of the neighboring L ligands. Furthermore, the thermal stability and fluorescence properties of the complex are investigated.

Keywords

crystal structure fluorescence property hydrothermal synthesis Zn(II) complex 

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References

  1. 1.
    H. Furukawa, N. Ko, Y. B. Go, O. M. Yaghi, et al. Science, 2010, 329, 424–428.CrossRefGoogle Scholar
  2. 2.
    S. R. Batten, N. R. Champness, J. Reedijk, et al. CrystEngComm, 2012, 14, 3001.CrossRefGoogle Scholar
  3. 3.
    D. Y. Du, J. S. Qin, Y. Q. Lan, et al. Chem. Soc. Rev., 2014, 43, 4615.CrossRefGoogle Scholar
  4. 4.
    J. D. Evans, C. J. Sumby, C. J. Doonan, et al. Chem. Soc. Rev., 2014, 43, 5933.CrossRefGoogle Scholar
  5. 5.
    K. J. Gagnon, H. P. Perry, A. Clearfield, et al. Chem. Rev., 2012, 112, 1034–1054.CrossRefGoogle Scholar
  6. 6.
    Y. Han, J. R. Li, G. Guo, et al. Chem. Soc. Rev., 2014, 43, 5952.CrossRefGoogle Scholar
  7. 7.
    J. R. Li, J. Sculley, H. C. Zhou, et al. Chem. Rev., 2012, 112, 869–932.CrossRefGoogle Scholar
  8. 8.
    W. Lu, Z. Wei, H. C. Zhou, et al. Chem. Soc. Rev., 2014, 43, 5561.CrossRefGoogle Scholar
  9. 9.
    P. Ramaswamy, N. E. Wong, G. K. H. Shimizu, et al. Chem. Soc. Rev., 2014, 43, 5913.CrossRefGoogle Scholar
  10. 10.
    X. Zhang, Y. Q. Zhao, G. Y. Dong, et al. Z. Anorg. Allg. Chem., 2016, 642, 36–40.CrossRefGoogle Scholar
  11. 11.
    X. X. Wang, Y. N. Zhao, G. H. Cui, et al. Transition Met. Chem., 2014, 39, 875–882.CrossRefGoogle Scholar
  12. 12.
    J. M. Hao, B. Y. Yu, G. H. Cui, et al. CrystEngComm, 2015, 17, 2279–2293.CrossRefGoogle Scholar
  13. 13.
    S. Y. Hao, Y. G. Liu, Z. C. Hao, et al. Z. Anorg. Allg. Chem., 2016, 42, 618–625.CrossRefGoogle Scholar
  14. 14.
    L. Z. Zhao, P. Li, B. L. Cao, et al. Acta Crystallogr., Sect. E: Struct. Rep. Online, 2009, 65, m613.CrossRefGoogle Scholar
  15. 15.
    J. Fan, G. T. Yee, G. Wang, et al. Inorg. Chem., 2006, 45, 599–608.CrossRefGoogle Scholar
  16. 16.
    R. den Hartog, M. R. Harvey, J. J. Hummel, et al. Inorg. Chem., 2011, 376, 664–670.Google Scholar
  17. 17.
    L. Raehm, L. Mimassi, C. Guyard Duhayon, et al. Inorg. Chem., 2003, 42, 5654–5659.CrossRefGoogle Scholar
  18. 18.
    J. Li, L. Li, H. Hou, et al. J. Organomet. Chem., 2009, 694, 1359–1368.CrossRefGoogle Scholar
  19. 19.
    Y. Chen, J. Yang, X. C. Wang, et al. RSC Adv., 2016, 6, 5729–5738.CrossRefGoogle Scholar
  20. 20.
    L. Qin, J. Zheng, G. H. Cui, et al. Inorg. Chem. Commun., 2013, 34, 71–74.CrossRefGoogle Scholar
  21. 21.
    G. M. Sheldrick. SADABS. University of Göttingen, Germany, 1996.Google Scholar
  22. 22.
    G. M. Sheldrick. Acta Crystallogr., Sect. D: Biol. Crystallogr., 2010, 66, 479–485.CrossRefGoogle Scholar
  23. 23.
    J. C. Geng, G. H. Cui, C. H. Jiao, et al. J. Chin. Chem. Soc., 2012, 59, 704–709.CrossRefGoogle Scholar
  24. 24.
    J. M. Hao, G. Y. Li, Y. H. Li, et al. Spectrochim. Acta, Part A, 2014, 131, 102–108.CrossRefGoogle Scholar
  25. 25.
    Y. Cui, Y. Yue, G. Qian, et al. Chem. Rev., 2012, 112, 1126–1162.CrossRefGoogle Scholar
  26. 26.
    H. Y. Bai, J. Yang, B. Liu, et al. CrystEngComm, 2011, 13, 5877–5884.CrossRefGoogle Scholar
  27. 27.
    C. V. Sastri, M. J. Park, T. Ohta, et al. J. Am. Chem. Soc., 2005, 127, 12494/12495.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • S. Y. Hao
    • 1
  • Z. C. Hao
    • 1
  • Y. G. Liu
    • 1
  • G. Y. Dong
    • 1
  1. 1.College of Chemical Engineering, Hebei Key Laboratory for Environment Photocatalytic and Electrocatalytic MaterialsNorth China University of Science and TechnologyTangshan, HebeiP. R. China

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