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Journal of Structural Chemistry

, Volume 56, Issue 4, pp 765–768 | Cite as

Crystal structure of the seven-electron molybdenum cluster [Mo3S4(dppe)3Cl3]∙3.5C4H8O2∙0.5Et2O

  • P. A. PetrovEmail author
  • G. A. Sosnin
  • D. Yu. Naumov
  • S. N. Konchenko
Brief Communications

Abstract

The seven-electron neutral cluster complex [Mo3S4(dppe)3Cl3] (dppe = Ph2PCH2CH2PPh2) is obtained by the reduction of the [Mo3S4(dppe)3Cl3]Cl cluster with gallium metal. The molecular and crystal structure of [Mo3S4(dppe)3Cl3]∙3.5C4H8O2∙0.5Et2O solvate is determined by single crystal XRD. The crystallographic data are as follows: monoclinic crystal symmetry, space group C2/c, a = 41.1775(16) Å, b = 17.7178(7) Å, c = 28.9609(9) Å, β = 110.363(1)°, V = 19808.7(13) Å3, Z = 8, d calc = 1.384 g/cm3.

Keywords

cluster complexes molybdenum sulfur single crystal X-ray diffraction study 

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References

  1. 1.
    J. B. Howard and D. C. Rees, Chem. Rev., 96, 2965–2982 (1996).CrossRefGoogle Scholar
  2. 2.
    H. Seino and M. Hidai, Chem. Sci., 2, 847–857 (2011).CrossRefGoogle Scholar
  3. 3.
    I. Sorribes, G. Wienhöfer, C. Vicent, et al., Angew. Chem., Int. Ed., 51, 7794–7798 (2012).CrossRefGoogle Scholar
  4. 4.
    T. F. Beltrán, M. Feliz, R. Llusar, et al., Organometallics, 30, 290–297 (2011).CrossRefGoogle Scholar
  5. 5.
    R. Llusar, S. Uriel, C. Vicent, et al., J. Am. Chem. Soc., 126, 12071–12083 (2004).CrossRefGoogle Scholar
  6. 6.
    M. Feliz, R. Llusar, S. Uriel, et al., Chem. Eur. J., 10, 4308–4314 (2004).CrossRefGoogle Scholar
  7. 7.
    A. L. Gushchin, R. Llusar, C. Vicent, et al., Eur. J. Inorg. Chem., 2615–2622 (2013).Google Scholar
  8. 8.
    W. Beck, W. Danzer, and G. Thiel, Angew. Chem. Int., Ed. Engl., 12, 582 (1973).Google Scholar
  9. 9.
    R. E. Cramer, K. Yamada, H. Kawaguchi, and K. Tatsumi, Inorg. Chem., 35, 1743–1746 (1996).CrossRefGoogle Scholar
  10. 10.
    J. Mizutani, H. Imoto, and T. Saito, J. Cluster Sci., 6, 523–532 (1995).CrossRefGoogle Scholar
  11. 11.
    P. A. Petrov, D. Yu. Naumov, R. Llusar, et al., Dalton Trans., 41, 14031–14034 (2012).CrossRefGoogle Scholar
  12. 12.
    P. A. Petrov, A. I. Smolentsev, and S. N. Konchenko, Russ. J. Coord. Chem., 39, 510–513 (2013).CrossRefGoogle Scholar
  13. 13.
    A. Gordon and R. Ford, The Chemist's Companion, Wiley, New York–London (1972).Google Scholar
  14. 14.
    V. P. Fedin, M. N. Sokolov, Yu. V. Mironov, et al., Inorg. Chim. Acta, 167, 39–45 (1990).CrossRefGoogle Scholar
  15. 15.
    APEX2 (Version 1.08), SAINT (Version 7.03), SADABS (Version 2.11), SHELXTL (Version 6.12), Bruker AXS Inc., Madison, Wisconsin, USA (2004).Google Scholar
  16. 16.
    F. Estevan, M. Feliz, R. Llusar, et al., Polyhedron, 20, 527–535 (2001).CrossRefGoogle Scholar
  17. 17.
    R. Frantz, E. Guillamón, J. Lacour, et al., Inorg. Chem., 46, 10717–10723 (2007).CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2015

Authors and Affiliations

  • P. A. Petrov
    • 1
    • 2
    Email author
  • G. A. Sosnin
    • 2
  • D. Yu. Naumov
    • 1
  • S. N. Konchenko
    • 1
    • 2
  1. 1.Nikolaev Institute of Inorganic Chemistry, Siberian BranchRussian Academy of SciencesNovosibirskRussia
  2. 2.Novosibirsk National Research State UniversityNovosibirskRussia

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