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Journal of Structural Chemistry

, Volume 55, Issue 8, pp 1453–1465 | Cite as

Protonated diamines as linkers in the supramolecular assemblies based on the [V12B18O60H6] polyoxovanadoborate anion

  • P. Hermosilla-Ibáñez
  • J. Costamagna
  • A. Vega
  • V. Paredes-García
  • M. T. Garland
  • E. Le Fur
  • E. Spodine
  • D. Venegas-Yazigi
Self-Organization in Molecular and Supramolecular Compounds

Abstract

Two new polyoxovanadoborates based crystalline lattices are being reported: K5(H3O)2(1,3-diapH2)2[V12B18O60H6]·10.80H2O (1), and K2(H3O)7(enH2)[V12B18O60H6]·9H2O (2). These structures are characterized by presenting multiple hydrogen bonds between the diprotonated diamines (enH2 and 1,3-diapH2) and hydronium ions, and the oxygen atoms of the [V12B18O60H6] cluster. The crystalline packing and stability of these new polyoxovanadoborates is dominated by the different types of hydrogen interactions present in the lattices ranging from unidirectional to trifurcated ones. The crystallographic data, together with the BVS method, permit to assign a mixed valence ratios for the [V12B18O60H6] anionic cluster for (1) and (2) being 11/1 (VIV/VV) ratio.

Keywords

polyoxometalate polyoxovanadate supramolecular mixed valence BVO 

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Copyright information

© Pleiades Publishing, Ltd. 2014

Authors and Affiliations

  • P. Hermosilla-Ibáñez
    • 1
    • 2
  • J. Costamagna
    • 1
  • A. Vega
    • 2
    • 3
  • V. Paredes-García
    • 2
    • 3
  • M. T. Garland
    • 4
  • E. Le Fur
    • 5
    • 6
  • E. Spodine
    • 2
    • 7
  • D. Venegas-Yazigi
    • 1
    • 2
  1. 1.Facultad de Química y Biología, Universidad de Santiago de ChileUSACHSantiagoChile
  2. 2.CEDENNASantiagoChile
  3. 3.Departamento de Ciencias Químicas, Facultad de Ciencias ExactasUniversidad Andres BelloSantiagoChile
  4. 4.Facultad de Ciencias Físicas y MatemáticasUniversidad de ChileSantiagoChile
  5. 5.ENSCR, CNRS, UMR 6226RennesFrance
  6. 6.Université Européenne de BretagneRennesFrance
  7. 7.Facultad de Ciencias Químicas y FarmacéuticasUniversidad de ChileSantiagoChile

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