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Journal of Structural Chemistry

, Volume 55, Issue 2, pp 370–373 | Cite as

Crystal and molecular structure of 1-(3-ammoniopropyl)silatrane chloride

  • M. G. Voronkov
  • È. A. Zel’bst
  • V. S. Fundamensky
  • V. V. Gurzhiy
  • Yu. I. Bolgova
  • O. M. Trofimova
Brief Communications

Abstract

By single crystal X-ray diffraction the crystal and molecular structure of 1-(3-ammoniopropyl)silatrane chloride (I) is determined. One of three cations in the asymmetric unit of the crystal of I differs from the other two by the length of the coordination N → Si bond. The opposite electronic effects in two geometrically similar cations are transferred inductively through a three-carbon chain.

Keywords

1-(3-ammoniopropyl)silatrane chloride molecular structure single crystal X-ray diffraction study 

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Copyright information

© Pleiades Publishing, Ltd. 2014

Authors and Affiliations

  • M. G. Voronkov
    • 1
  • È. A. Zel’bst
    • 2
  • V. S. Fundamensky
    • 3
  • V. V. Gurzhiy
    • 3
  • Yu. I. Bolgova
    • 1
  • O. M. Trofimova
    • 1
  1. 1.Favorsky Institute of Chemistry, Siberian BranchRussian Academy of SciencesIrkutskRussia
  2. 2.East Siberian State Academy of EducationIrkutskRussia
  3. 3.Saint-Petersburg State Institute of TechnologySaint-PetersburgRussia

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