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Journal of Structural Chemistry

, Volume 53, Issue 2, pp 354–360 | Cite as

Molecular interactions in 2-aminopyridinium malonate

  • R. Chitra
  • P. Rousse
  • F. Capet
  • G. J. Abraham
  • R. R. Choudhury
Article

Abstact

A new complex of 2-aminopyridine and malonic acid in a 1:1 stoichiometric ratio is obtained. The complex crystallizes in a centrosymmetric P21/c space group with a = 3.8522(2)Å, b = 17.5226(8)Å, c = 13.7317(7)Å and β = 94.418(3)°. This complex is held by network of hydrogen bonds between the protonated 2-aminopyridinium cation and the malonate anion. There is no phase transition observed in this complex, which is verified using DSC and single crystal X-ray measurement studies. Unlike 2-aminopyridinium maleate, this complex crystallizes in the centrosymmetric space group and hence, this complex will not exhibit any non-linear optical property.

Keywords

2-aminopyridinium malonate single crystal X-ray diffraction Raman scattering DSC IR 

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Copyright information

© Pleiades Publishing, Ltd. 2012

Authors and Affiliations

  • R. Chitra
    • 1
  • P. Rousse
    • 2
  • F. Capet
    • 2
  • G. J. Abraham
    • 3
  • R. R. Choudhury
    • 1
  1. 1.Solid State Physics DivisionBhabha Atomic Research CenterTrombayIndia
  2. 2.UCCS, CNRS UMR 8181ENSC Lille USTLilleFrance
  3. 3.Material Science DivisionBhabha Atomic Research CenterTrombayIndia

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