Recovery of Methane From Gas Hydrates in a Porous Medium by Injection of Carbon Dioxide

  • I. K. GimaltdinovEmail author
  • M. V. Stolpovskii
  • M. K. Khasanov


This paper presents a mathematical model for methane hydrate–carbon dioxide replacement by injection of carbon dioxide gas into a porous medium rich in methane and its gas hydrate. Numerical solutions describing the pressure and temperature variation in a reservoir of finite length are obtained. It is shown that the replacement process is accompanied by a decrease in pressure and an increase in temperature of the porous medium. It is established that during the time of complete replacement of methane from a reservoir decreases with increasing permeability of the porous medium and the pressure of the injected gas.


porous medium gas hydrate filtration 


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.


  1. 1.
    X. T. Zhou, S. S. Fan, and D. Q. Liang, “Advancement in Research on Replacement of CH4 from Hydrate with CO2,” Chem. Industr. Eng. Process. 25, 524–527 (2006).Google Scholar
  2. 2.
    K. Ohgaki, K. Takano, H. Sangawa, et al., “Methane Exploitation by Carbon Dioxide from Gas Hydrates-Phase Equilibria for CO2–CH4 Mixed Hydrate System,” J. Chem. Eng. 29 (3), 478–483 (1996).CrossRefGoogle Scholar
  3. 3.
    N. Goel, “In Situ Methane Hydrate Dissociation with Carbon Dioxide Sequestration: Current Knowledge and Issues,” J. Petrol. Sci. Eng. 51, 169–184 (2006).CrossRefGoogle Scholar
  4. 4.
    S. Nakano, K. Yamamoto, and K. Ohgaki, “Natural Gas Exploitation by Carbon Dioxide from Gas Hydrate Fields-High-Pressure Phase Equilibrium for an Methane Hydrate System,” Proc. Inst. Mech. Eng. 212, 159–163 (1998).CrossRefGoogle Scholar
  5. 5.
    J. W. Jung and J. C. Santamarina, “A Pore-Scale Study,” Geochem., Geophys., Geosyst. 11, Q0AA13 (2010).CrossRefGoogle Scholar
  6. 6.
    J. W. Jung, D. N. Espinoza, and J. C. Santamarina, “Properties and Phenomena Relevant to CH4–CO2 Replacement in Hydrate-Bearing Sediments,” J. Geophys. Res. 115, B10102 (2010).ADSCrossRefGoogle Scholar
  7. 7.
    Qing Yuan, Chang-Yu Sun, Bei Liu, et al., “Methane Recovery from Natural Gas Hydrate in Porous Sediment Using Pressurized Liquid CO2,” Energy Convers. Management 67, 257–264 (2013).CrossRefGoogle Scholar
  8. 8.
    V. P. Voronov, E. E. Gorodetskii, B. A. Grigor’ev, and A. F. Muratov, “Experimental Study of Methane Replacement by Carbon Dioxide in Gas Hydrate,” Vesti Gaz. Nauki, No. 2, 235–248 (2011).Google Scholar
  9. 9.
    V. Sh. Shagapov, N. G. Musakaev, and M. K. Khasanov, “Formation of Gas Hydrates in a Porous Medium during an Injection of Cold Gas,” Int. J. Heat Mass Transfer 84, 1030–1039 (2015).CrossRefGoogle Scholar
  10. 10.
    M. K. Khasanov, I. K. Gimaltdinov, and M. V. Stolpovskii, “Features of the Formation of Gas Hydrates by Cold Gas Injection into a Porous Medium Saturated with Gas and Water,” Teor. Osn. Khim. Tekhnol. 44 (4), 442–449 (2010).Google Scholar
  11. 11.
    V. Sh. Shagapov, M. K. Khasanov, I. K. Gimaltdinov, and M. V. Stolpovskii, “Decomposition of Gas Hydrates in Porous Media under Injection of Hot Gas,” Teplofiz Aeromech. 20 (3), 347–354 (2013).CrossRefGoogle Scholar
  12. 12.
    M. K. Khasanov, N. G. Musakaev, and I. K. Gimaltdinov, “Features of the Decomposition of Gas Hydrates with the Formation of Ice in a Porous Medium,” Inzh.-Fiz. Zh. 88 (5), 1022–1030 (2015).Google Scholar
  13. 13.
    G. G. Tsypkin, “On the Dissociation of Gas Hydrates in Highly Permeable Formations,” Inzh.-Fiz. Zh. 63 (6), 714–721 (1992).Google Scholar
  14. 14.
    G. G. Tsypkin, “Regime of Dissociation of Gas Hydrates Coexisting with a Gas in Natural Strata,” Inzh.-Fiz. Zh. 74 (5), 24–28 (2001).Google Scholar
  15. 15.
    V. I. Vasil’ev, V. V. Popov, and G. G. Tsypkin, “Numerical Investigation of the Decomposition of Gas Hydrates Coexisting with Gas in Natural Reservoirs,” Izv. Ross. Akad. Nauk, Mekh. Zhidk. Gaza, No. 4, 127–134 (2006).zbMATHGoogle Scholar
  16. 16.
    G. G. Tsypkin, “A Mathematical Model of Carbon Dioxide Flooding with Hydrate Formation,” Dokl. Akad. Nauk 458 (4), 422–425 (2014).Google Scholar
  17. 17.
    G. G. Tsypkin, “Formation of Carbon Dioxide Hydrate at the Injection of Carbon Dioxide into a Depleted Hydrocarbon Field,” Izv. Ross. Akad. Nauk, Mekh. Zhidk. Gaza, No. 6, 101–108 (2014).zbMATHGoogle Scholar
  18. 18.
    V. A. Istomin and V. S. Yakushev, Gas Hydrates in Nature (Nedra, Moscow, 1992) [in Russian].Google Scholar
  19. 19.
    G. I. Barenblatt, V. M. Entov, and V. M. Ryzhik, Motion of Liquids and Gases in Natural Reservoirs (Nedra, Moscow, 1982) [in Russian].Google Scholar
  20. 20.
    V. I. Vasil’ev, V. V. Popov, and T. S. Timofeeva, Computational Methods in the Development of Oil and Gas Fields (Izd. Sib. Otd. Ross. Akad. Nauk, Novosibirsk, 2000) [in Russian].Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • I. K. Gimaltdinov
    • 1
    Email author
  • M. V. Stolpovskii
    • 1
  • M. K. Khasanov
    • 2
  1. 1.Ufa State Oil Technical UniversityUfaRussia
  2. 2.Sterlitamak Branch of Bashkir State UniversitySterlitamakRussia

Personalised recommendations