JETP Letters

, Volume 96, Issue 6, pp 370–374

Structure and transport properties of stephanite (Ag5SbS4) according to antimony nuclear quadrupole resonance

  • A. Yu. Orlova
  • R. R. Gainov
  • A. V. Dooglav
  • I. N. Pen’kov
  • E. A. Korolev
Article

Abstract

Silver sulfo-antimonide Ag5SbS4 (stephanite) has been studied by nuclear quadrupole resonance (NQR) spectroscopy on antimony nuclei. The temperature dependences of the spectroscopic and relaxation parameters have been examined in the range of 4.2–395 K. A phase transition at 140 K and internal motions with an activation energy of 0.29 eV have been experimentally detected. The nature of the phase transition and diffusion of silver ions has been discussed in view of the reported data.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    H. Dittrich, A. Stadler, D. Topa, et al., Phys. Status Solidi A 206, 1034 (2009).ADSCrossRefGoogle Scholar
  2. 2.
    K. A. Schonau and S. T. Redfern, J. Appl. Phys. 92, 7415 (2002).ADSCrossRefGoogle Scholar
  3. 3.
    L. Bindi, M. Evani, and S. Menchetti, Acta. Cryst. B 62, 212 (2006).CrossRefGoogle Scholar
  4. 4.
    D. F. Baisa and S. V. Mal’tsev, J. Mol. Struct. 83, 387 (1982).ADSCrossRefGoogle Scholar
  5. 5.
    G. D. Boyd, J. H. McFee, and F. H. Wehmeier, Appl. Phys. Lett. B 16, 59 (1970).ADSCrossRefGoogle Scholar
  6. 6.
    D. F. Baisa, A. V. Bondar, and A. Ja. Gordon, Ferroelectrics 20, 219 (1978).CrossRefGoogle Scholar
  7. 7.
    V. S. Grechishkin, Nuclear Quadrupole Interactions in Solids (Nauka, Moscow, 1973) [in Russian].Google Scholar
  8. 8.
    R. S. Abdullin, I. N. Pen’kov, N. M. Nizamutdinov, et al., Sov. Phys. Solid State 19, 948 (1977).Google Scholar
  9. 9.
    A. A. Petrunina, B. A. Maksimov, V. V. Ilyukhin, et al., Sov. Phys. Dokl. 14, 833 (1969).ADSGoogle Scholar
  10. 10.
    I. N. Pen’kov and I. A. Safin, Dokl. Akad. Nauk SSSR 168, 1148 (1966).Google Scholar
  11. 11.
    R. R. Gainov, A. V. Dooglav, I. N. Pen’kov, et al., Superconductor (Sciyo, Rijeka, Croatia, 2010).Google Scholar
  12. 12.
    P. S. Zyryanov and V. I. Okulov, Sov. Phys. Solid State 6, 1957 (1964).Google Scholar
  13. 13.
    N. V. Belov, A. A. Godovikov, and V. V. Bakakin, Essays on Theoretical Mineralogy (Nauka, Moscow, 1982) [in Russian].Google Scholar
  14. 14.
    A. Abragam, The Principles of Nuclear Magnetism (Clarendon, Oxford, 1961).Google Scholar
  15. 15.
    D. F. Baisa, A. I. Barabash, and I. G. Vertegel’, Ukr. Fiz. Zh. 26, 1 (1981).Google Scholar
  16. 16.
    M. Leitl, A. Pfitzner, and L. Bindi, Mineralogic. Mag. 73, 17 (2009).CrossRefGoogle Scholar
  17. 17.
    N. I. Butsko, I. D. Zhezhnich, and M. M. Pidorya, Russ. Phys. J. 16, 223 (1973).Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2012

Authors and Affiliations

  • A. Yu. Orlova
    • 1
  • R. R. Gainov
    • 1
  • A. V. Dooglav
    • 1
  • I. N. Pen’kov
    • 2
  • E. A. Korolev
    • 2
  1. 1.Institute of PhysicsKazan Federal UniversityKazanRussia
  2. 2.Institute of Geology and Petroleum TechnologiesKazan Federal UniversityKazanRussia

Personalised recommendations