Inorganic Materials

, Volume 55, Issue 11, pp 1162–1166 | Cite as

Synthesis and Luminescence Properties of a Li3Ba2Y3(MoO4)8:Tb3+ Phosphor with a Layered Scheelite-Like Structure

  • N. M. KozhevnikovaEmail author
  • S. Yu. Batueva

Abstract—We have synthesized a Li3Ba2Y3(MoO4)8:Tb3+ phosphor with a scheelite-like structure (sp. gr. C2/c) and studied its luminescence properties. The material has been characterized by X-ray diffraction, differential thermal analysis, and IR spectroscopy.


phase equilibria Li2MoO4–BaMoO4–Y2(MoO4)3 system ternary molybdate terbium ion luminescence 



This work was supported by the Russian Federation Ministry of Science and Higher Education (state research target for the Baikal Institute of Nature Management, Siberian Branch, Russian Academy of Sciences, project no. 0339-2016-007).


  1. 1.
    Kaminskii, A.A., Spektroskopiya kristallov (Spectroscopy of Crystals), Moscow: Nauka, 1975.Google Scholar
  2. 2.
    Kozhevnikova, N.M. and Mokhosoev, M.V., Troinye molibdaty (Ternary Molybdates), Ulan-Ude: Buryatsk. Gos. Univ., 2000.Google Scholar
  3. 3.
    Kozhevnikova, N.M. and Kopylova, O.A., Synthesis and X-ray diffraction and IR spectroscopy studies of ternary molybdates Li3Ba2R3(MoO4)8 (R = La–Lu, Y), Russ. J. Inorg. Chem., 2011, vol. 56, no. 6, pp. 935–938.CrossRefGoogle Scholar
  4. 4.
    Kozhevnikova, N.M., Korsun, V.P., Mursakhanova, I.I., and Mokhosoev, M.V., Luminescence materials based on RE molybdates, J. Rare Earths, 1991, vol. 2, pp. 845–849.Google Scholar
  5. 5.
    Klevtsova, R.F., Vasil’ev, A.D., Glinskaya, L.A., et al., Crystal structure of the Li3Ba2R3(MoO4)8 (R = Gd, Tu) ternary molybdates, Zh. Strukt. Khim., 1992, vol. 33, no. 3, pp. 126–130.Google Scholar
  6. 6.
    Trunov, V.K., Efremov, V.A., and Velikodnyi, Yu.A., Kristallokhimiya i svoistva dvoinykh molibdatov i vol’framatov (Crystal Chemistry and Properties of Double Molybdates and Tungstates), Leningrad: Nauka, 1986.Google Scholar
  7. 7.
    Petrov, K.I., Poloznikova, M.E., Sharipov, Kh.T., and Fomichev, V.V., Kolebatel’nye spektry molibdatov i vol’framatov (Vibrational Spectra of Molybdates and Tungstates), Tashkent: FAN, 1990.Google Scholar
  8. 8.
    Maliarevich, G.K., Gaponenko, N.V., Mudryi, A.V., et al., Terbium photoluminescence in yttrium aluminum garnet xerogels, Semiconductors, 2009, vol. 43, no. 2, pp. 158–161.CrossRefGoogle Scholar
  9. 9.
    Tsyretarova, S.Yu., Kozhevnikova, N.M., and Eremina, N.S., Red and green phosphors based on Eu3+- and Tb3+-doped oxide glass-ceramics, Materialy mezhdunarodnoi nauchnoi konferentsii “Polifunktsional’nye Khimicheskie Materialy i Tekhnologii” (Proc. Int. Sci. Conf. Polyfunctional Chemical Materials and Technologies), 2015, vol. 2, pp. 264–267.Google Scholar
  10. 10.
    Anthuvan, J.P. and Shameem Banu, I.B., Synthesis and luminescent properties of Tb3+ activated Li3Ba2Gd3 – x(MoO4)8 based efficient green emitting phosphors, J. Appl. Sci. Eng., 2016, vol. 19, no. 4, pp. 409–412.Google Scholar
  11. 11.
    Xinyu Li, Chunxin Liang, and Shaojie Guo, Photoluminescence and afterglow behavior of Tb3+ activated Li2SrSiO4 phosphor, J. Lumin., 2017, vol. 188, pp. 199–203.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  1. 1.Baikal Institute of Nature Management, Siberian Branch, Russian Academy of SciencesUlan-UdeRussia

Personalised recommendations