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High Energy Chemistry

, Volume 52, Issue 5, pp 378–383 | Cite as

Photoreduction of 9,10-Phenanthrenequinone in the Presence of Dimethacrylate Oligomers and Their Polymers

  • N. A. Len’shina
  • M. Yu. Zakharina
  • R. S. Kovylin
  • M. A. Baten’kin
  • T. I. Kulikova
  • M. V. Arsen’ev
  • S. A. Chesnokov
Photochemistry

Abstract

The effective rate constants for the photoreduction (kH) of 9,10-phenanthrenequinone (PQ) in the presence of dimethacrylate monomers (ethylene glycol dimethacrylate (DMEG), triethylene glycol dimethacrylate (TGM-3), and oligocarbonate dimethacrylate (OKM-2)) and porous polymers based on them have been spectrophotometrically determined. The values of kH in the presence of DMEG and TGM-3 in benzene solutions and in the monomer media are two times greater than in the presence of OKM-2. The values of kH for PQ in pores of polyDMEG, polyTGM-3, and polyOKM-2 are approximately identical and do not depend on the pore size (up to hundreds of nanometers) and the specific surface area.

Keywords

photoreduction 9,10-phenanthrenequinone oligomer methacrylate porous polymer 

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • N. A. Len’shina
    • 1
  • M. Yu. Zakharina
    • 1
  • R. S. Kovylin
    • 1
  • M. A. Baten’kin
    • 1
  • T. I. Kulikova
    • 1
  • M. V. Arsen’ev
    • 1
  • S. A. Chesnokov
    • 1
  1. 1.Razuvaev Institute of Organometallic ChemistryNizhny NovgorodRussia

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