High Energy Chemistry

, Volume 52, Issue 5, pp 446–448 | Cite as

The Quantum Yield of Singlet Oxygen in Thermal Degradation of Alcohol Hydrotrioxides

  • L. R. Khalitova
  • A. V. Antipin
  • S. A. GrabovskiiEmail author
  • N. N. Kabal’nova


The yield of singlet oxygen (1О2) in the decomposition of a number of hydrotrioxides of alcohols (cyclobutanol, cyclopentanol, cyclohexanol, cycloheptanol, cyclooctanol, L-menthol, 1,7,7-trimethylbicyclo[2.2.1]heptan-2-ol, 1,3,3-trimethylbicyclo[2.2.1]heptan-2-ol, heptan-4-ol, propanol-2, and 1-cyclopropylethanol) has been determined using the IR chemiluminescence technique. It has been shown that cyclopentanol, 1,3,3-trimethylbicyclo[2.2.1]heptan-2-ol and 1-cyclopropylethanol hydrotrioxides are efficient sources of singlet oxygen; the yield of 1О2 reaches up to 58%.


singlet oxygen hydrotrioxides chemiluminescence 


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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • L. R. Khalitova
    • 1
  • A. V. Antipin
    • 1
  • S. A. Grabovskii
    • 1
    Email author
  • N. N. Kabal’nova
    • 1
  1. 1.Ufa Institute of Chemistry, Ufa Federal Research CenterRussian Academy of SciencesUfaRussia

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