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High Energy Chemistry

, Volume 51, Issue 3, pp 209–214 | Cite as

Photoreduction of o-benzoquinone moiety in mono- and poly(quinone methacrylate) and on the surface of polymer matrix pores

  • N. A. Len’shina
  • M. V. Arsenyev
  • M. P. ShuryginaEmail author
  • S. A. Chesnokov
  • G. A. Abakumov
Photochemistry

Abstract

The kinetics of photoreduction under the action of visible light of the 3,6-di-tert-butyl-o-benzoquinone moiety in methacrylic monomer, polymer, and in the graft layer on the surface of pores in the presence of different N,N-dimethylanilines has been studied. The reaction is accelerated with the increasing electron-donating ability of the amine. In the presence of N,N-dimethylaniline at 50-fold molar excess of the amine, the photoreduction in the porous polymer occurs three and four times faster than in the monomer and the polymer, respectively.

Keywords

photoreduction o-benzoquinone poly-o-benzoquinone porous polymer N,N-dimethylaniline 

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Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • N. A. Len’shina
    • 1
  • M. V. Arsenyev
    • 1
  • M. P. Shurygina
    • 1
    Email author
  • S. A. Chesnokov
    • 1
  • G. A. Abakumov
    • 1
  1. 1.Razuvaev Institute of Organometallic ChemistryRussian Academy of SciencesNizhny NovgorodRussia

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