High Energy Chemistry

, Volume 49, Issue 1, pp 53–57

Reactions on single-walled nanotubes: 2. Reactions on the nanosized surface of nanotubes in liquid hydrocyanic acid

  • A. G. Ryabenko
  • D. P. Kiryukhin
  • G. A. Kichigina
  • O. M. Zhigalina
  • S. N. Sul’yanov
  • E. N. Nikolaev
  • M. N. Larichev
  • S. S. Bukalov
  • A. N. Krasnovskii
Nanostructured Systems and Materials

DOI: 10.1134/S0018143915010130

Cite this article as:
Ryabenko, A.G., Kiryukhin, D.P., Kichigina, G.A. et al. High Energy Chem (2015) 49: 53. doi:10.1134/S0018143915010130
  • 44 Downloads

Abstract

Chemical reactions stimulated by γ-radiation in liquid hydrocyanic acid (HCN) in the presence of single-walled edcarbon nanotubes (SWCNTs) have been studied. The polymerization of HCN on the surface of nanotubes occurs several times more rapidly than in pure HCN, and the set of radiolysis products becomes poorer. It is likely that the approach of polymerizing reagents on the nanosized surface is limited by specific mutual orientations. Furthermore, the CN and H radicals add to the walls of the nanotubes and the nanotubes become soluble in water, ethanol, and acids.

Copyright information

© Pleiades Publishing, Ltd. 2015

Authors and Affiliations

  • A. G. Ryabenko
    • 1
  • D. P. Kiryukhin
    • 1
  • G. A. Kichigina
    • 1
  • O. M. Zhigalina
    • 2
  • S. N. Sul’yanov
    • 2
  • E. N. Nikolaev
    • 3
  • M. N. Larichev
    • 3
  • S. S. Bukalov
    • 4
  • A. N. Krasnovskii
    • 5
  1. 1.Institute of Problems of Chemical PhysicsRussian Academy of SciencesChernogolovka, Moscow oblastRussia
  2. 2.Shubnikov Institute of CrystallographyRussian Academy of SciencesMoscowRussia
  3. 3.Tal’rose Institute of Energy Problems of Chemical PhysicsMoscowRussia
  4. 4.Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussia
  5. 5.Moscow State Technological Institute STANKINMoscowRussia

Personalised recommendations