Doklady Chemistry

, Volume 483, Issue 2, pp 304–307 | Cite as

Crystal Structure of Two-Dimensional Coordination Polymer {[Cu(dps)2(DMSO)2](ClO4)2}n Derived from 4,4'-Dipyridyl Sulfide

  • Yu. P. TupolovaEmail author
  • I. N. Shcherbakov
  • L. D. Popov
  • V. V. Tkachev
  • V. A. Chetverikova
  • G. V. Shilov
  • S. M. Aldoshin


A new complex of general formula {[Cu(dps)2(DMSO)2](ClO4)2}n has been obtained with the aim to study the effect of perchlorate anion on the structure of coordination polymer based on 4,4'-dipyridyl sulfide. It has been established by X-ray diffraction that the compound has a layered 2D polymer structure. Each copper(II) ion is in a pseudo-octahedral donor environment. Perchlorate anions are disposed in the network voids of the polymer complex.



This work was supported by the Southern Federal University (internal grant no. VnGr–07/2017–29) and the Federal Agency of Scientific Organizations (State registration no. 0089–2014–0009).


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Copyright information

© Pleiades Publishing, Inc. 2018

Authors and Affiliations

  • Yu. P. Tupolova
    • 1
    Email author
  • I. N. Shcherbakov
    • 1
  • L. D. Popov
    • 1
  • V. V. Tkachev
    • 2
  • V. A. Chetverikova
    • 1
  • G. V. Shilov
    • 2
  • S. M. Aldoshin
    • 2
  1. 1.Southern Federal UniversityRostov-on-DonRussia
  2. 2.Institute of Problems of Chemical Physics, Russian Academy of SciencesChernogolovkaRussia

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