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Doklady Chemistry

, Volume 483, Issue 1, pp 263–265 | Cite as

Methods of Creating closo-Decaborate Anion Derivatives with Bridging and Terminal Exopolyhedral Cyclic Substituents of Sulfonium Type

  • A. S. KubasovEmail author
  • E. Yu. Matveev
  • E. S. Turyshev
  • I. N. Polyakova
  • A. Yu. Bykov
  • A. V. Kopytin
  • K. Yu. Zhizhin
  • N. T. Kuznetsov
CHEMISTRY
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Abstract

New methods of creation of cyclic bridging and terminal exopolyhedral sulfur-containing substituents in the closo-decaborate anion have been suggested. It has been shown that the reaction of [B10H9SH]2– with 1,2-dibromoethane leads to crosslinking of two cluster anions to give the [B10H9S(CH2)4SB10H9]2– dimer. An analogous reaction with 1,4-dibromobutane yields a derivative with the cyclic tetrahydrothiophene substituent [B10H9S(CH2)4]. Its interaction with tetrahydrothiophene in the presence of a small excess of trifluoroacetic acid leads to the formation of the neutral disubstituted derivative [B10H8(S(CH2)4)2].

Notes

ACKNOWLEDGMENTS

This work was supported by the Russian Foundation for Basic Research (project no. 18–33–00158).

REFERENCES

  1. 1.
    Kubasov, A.S., Matveev, E.Yu., Polyakova, I.N., Razgonyaeva, G.A., Zhizhin, K.Yu., and Kuznetsov, N.T., Russ. J. Inorg. Chem., 2015, vol. 60, p. 198.CrossRefGoogle Scholar
  2. 2.
    Kubasov, A.S., Turishev, E.S., Polyakova, I.N., Matveev, E.Yu., Zhizhin, K.Yu., and Kuznetsov, N.T., J. Organomet. Chem., 2017, vol. 828, p. 106.CrossRefGoogle Scholar
  3. 3.
    Kubasov, A.S., Matveev, E.Yu., Turyshev, E.S., Polyakova, I.N., Nichugovskiy, A.I., Zhizhin, K.Yu., and Kuznetsov, N.T., Inorg. Chim. Acta, 2018, vol. 477, pp. 277–283.CrossRefGoogle Scholar
  4. 4.
    Matveev, E.Yu., Kubasov, A.S., Razgonyaeva, G.A., Polyakova, I.N., Zhizhin, K.Yu., and Kuznetsov, N.T., Russ. J. Inorg. Chem., 2015, vol. 60, p. 776.CrossRefGoogle Scholar
  5. 5.
    Klyukin, I.N., Zhdanov, A.P., Matveev, E.Yu., Razgonyaeva, G.A., Grigoriev, M.S., Zhizhin, K.Yu., and Kuznetsov, N.T., J. Inorg. Chem. Commun., 2014, vol. 50, p. 28.CrossRefGoogle Scholar
  6. 6.
    APEX2 (V. 2009, 5-1), SAINT (V7.60A), SADABS (2008/1), Bruker AXS, Inc., Madison (WI), 2008–2009.Google Scholar
  7. 7.
    Sheldrick, G.M., Acta Crystallogr., Sect. A, 2008, vol. 64, no. 1, p. 112.CrossRefGoogle Scholar
  8. 8.
    Bykov, A.Yu., Selivanov, N.A., Zhdanov, A.P., Zhizhin, K.Yu., and Kuznetsov, N.T., Fine Chem. Technol., 2016, vol. 11, p. 46.Google Scholar

Copyright information

© Pleiades Publishing, Inc. 2018

Authors and Affiliations

  • A. S. Kubasov
    • 1
    Email author
  • E. Yu. Matveev
    • 2
  • E. S. Turyshev
    • 3
  • I. N. Polyakova
    • 1
  • A. Yu. Bykov
    • 1
  • A. V. Kopytin
    • 1
  • K. Yu. Zhizhin
    • 1
    • 2
  • N. T. Kuznetsov
    • 1
  1. 1.Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of SciencesMoscowRussia
  2. 2.Moscow Technological UniversityMoscowRussia
  3. 3.Mendeleev University of Chemical Technology of RussiaMoscowRussia

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