Skip to main content
SpringerLink
Log in

Catalytic synthesis of O-aryl methyl(phenyl)phosphonochloridates

  • Chemistry
  • Published:
Doklady Chemistry Aims and scope Submit manuscript

Abstract

The reaction of methyl- and phenyldichlorophosphonates with phenols in the presence of anhydrous magnesium chloride (catalyst) or magnesium metal (procatalyst) has been used as a simple, efficient, and industrially feasible method for the synthesis of the corresponding O-aryl alkyl(aryl)phosphonochloridates.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Reddy, P.M., Viragh, C., and Kovach, I.M., Phosphorus, Sulfur Silicon, 2002, vol. 177, nos. 6/7, pp. 1597–1600.

    Article  CAS  Google Scholar 

  2. Kluger, R., Thatcher, G.R.J., and Stallings, W.C., Can. J. Chem., 1987, vol. 65, no. 8, pp. 1838–1844.

    Article  CAS  Google Scholar 

  3. Gefter, E.L., Zh. Obshch. Khim., 1961. vol. 31, no. 10, pp. 3316–3319.

    CAS  Google Scholar 

  4. Kabachnik, M.I., Zakharov, L.S., Goryunov, E.I., et al., Zh. Obshch. Khim., 1994, vol. 64, no. 6, pp. 902–912.

    CAS  Google Scholar 

  5. El Mastri, M. and Berlin, K.D., Org. Prep. Proc. Int., 1995, vol. 27, no. 2, pp. 161–169.

    Article  Google Scholar 

  6. Makarov, M.V., Leonova, E.S., Rybalkina, E.Yu., et al., Eur. J. Med. Chem., 2010, vol. 45, no. 3, pp. 992–1000.

    Article  CAS  Google Scholar 

  7. Leonova, E.S., Makarov, M.V., Rybalkina, E.Yu., et al., Eur. J. Med. Chem., 2010, vol. 45, no. 12, pp. 5926–5934.

    Article  CAS  Google Scholar 

  8. Marsi, K.L., VanderWerf, C.A., and McEwen, W.E., J. Am. Chem. Soc., 1956, vol. 78, no. 13, pp. 3063–3066.

    Article  CAS  Google Scholar 

  9. Hudson, R.F. and Keay, L., J. Chem. Soc., 1960, no. 4, pp. 1859–1864.

    Article  Google Scholar 

  10. Mel’nikov, N.N., Grapov, A.F., and Lebedeva, N.V., Zh. Obshch. Khim., 1966, vol. 36, no. 3, pp. 457–461.

    Google Scholar 

  11. Sharova, E.V., Genkina, G.K., Matveeva, E.V., et al., Izv. Akad. Nauk, Ser. Khim., 2014, no. 11, pp. 2546–2550.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, 119991, Russia

    V. K. Brel, E. I. Goryunov, G. N. Molchanova, I. B. Goryunova, I. Yu. Kudryavtsev, T. V. Baulina, A. A. Khodak, T. V. Strelkova & E. E. Nifant’ev

Authors
  1. V. K. Brel
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. I. Goryunov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. G. N. Molchanova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. I. B. Goryunova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. I. Yu. Kudryavtsev
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. T. V. Baulina
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. A. A. Khodak
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. T. V. Strelkova
    View author publications

    You can also search for this author in PubMed Google Scholar

  9. E. E. Nifant’ev
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to E. I. Goryunov.

Additional information

Original Russian Text © Goryunova, I.Yu. Kudryavtsev, T.V. Baulina, A.A. Khodak, T.V. Strelkova, E.E. Nifant’ev, 2017, published in Doklady Akademii Nauk, 2017, Vol. 472, No. 5, pp. 534–537.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Brel, V.K., Goryunov, E.I., Molchanova, G.N. et al. Catalytic synthesis of O-aryl methyl(phenyl)phosphonochloridates. Dokl Chem 472, 21–24 (2017). https://doi.org/10.1134/S001250081702001X

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S001250081702001X

Search

Navigation