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Technical Physics

, Volume 49, Issue 2, pp 143–153 | Cite as

Optical properties of metal nanoparticles synthesized in a polymer by ion implantation: A review

  • A. L. Stepanov
Article

Abstract

Polymer composite layers irradiated by 30-keV Ag+ ions with doses from 3.1×1015 to 7.5×1016 cm−2 and an ion current of 4 µA/cm2 are investigated. The composites were examined using Rutherford backscattering (RBS), transmission electron microscopy (TEM), and optical spectroscopy. As follows from electron microscopy and electron microdiffraction data, ion implantation is a promising tool for synthesizing silver nanoparticles in the surface region. The optical density spectra taken of these composites demonstrate that the silver nanoparticles exhibit unusually weak plasma resonance. The formation of silver nanoparticles in layers carbonized by ion implantation is considered. Based on the Mie theory, optical extinction spectra for silver particles in the polymer and carbon matrices are simulated and optical spectra for complex silver core-carbon sheath nanoparticles are calculated. The physics behind the experimental optical spectra of the composite is discussed.

Keywords

Silver Nanoparticles Optical Spectrum Optical Density Spectrum Silver Particle Composite Layer 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    V. V. Randoshkin and A. Ya. Chervonenkis, Applied Magnetooptics (Énergoizdat, Moscow, 1990).Google Scholar
  2. 2.
    A. L. Stepanov, R. I. Khaibullin, S. N. Abdullin, and I. B. Khaibullin, RF Patent No. 97,109,708 (1997).Google Scholar
  3. 3.
    S. Muto, T. Kubo, Y. Kurokawa, and K. Suzuki, Thin Solid Films 322, 233 (1998).CrossRefGoogle Scholar
  4. 4.
    U. Kreibig and M. Vollmer, Optical Properties of Metal Clusters (Springer, Berlin, 1995).Google Scholar
  5. 5.
    L. Minyung, S. K. Taek, and S. C. Young, J. Non-Cryst. Solids 211, 143 (1997).Google Scholar
  6. 6.
    S. N. Abdullin, A. L. Stepanov, Yu. N. Osin, and I. B. Khaibullin, Surf. Sci. 395, L242 (1998).CrossRefGoogle Scholar
  7. 7.
    M. Quinten, A. Heilmann, and A. Kiesow, Appl. Phys. B 68, 707 (1999).ADSGoogle Scholar
  8. 8.
    P. T. Townsend, P. J. Chandler, and L. Zhang, Optical Effects of Ion Implantation (Cambridge Univ. Press, Cambridge, 1994).Google Scholar
  9. 9.
    N. C. Koon, D. Weber, P. Penrsson, and A. I. Shindler, Mater. Res. Soc. Symp. Proc. 27, 4466 (1984).Google Scholar
  10. 10.
    Y. Wu, T. Zhang, Y. Zhang, et al., Nucl. Instrum. Methods Phys. Res. B 169, 89 (2000).CrossRefADSGoogle Scholar
  11. 11.
    Y. Wu, T. Zhang, Y. Zhang, et al., Nucl. Instrum. Methods Phys. Res. B 173, 292 (2001).CrossRefADSGoogle Scholar
  12. 12.
    K. Ogawa, US Patent No. 4,751,100 (1988).Google Scholar
  13. 13.
    R. I. Khaibullin, V. N. Popok, V. V. Bazarov, et al., Nucl. Instrum. Methods Phys. Res. B 191, 810 (2002).CrossRefADSGoogle Scholar
  14. 14.
    V. N. Popok, R. I. Khaibullin, V. V. Bazarov, et al., Nucl. Instrum. Methods Phys. Res. B 191, 695 (2002).CrossRefADSGoogle Scholar
  15. 15.
    V. Yu. Petukhov, V. A. Zhikharev, N. R. Khabibullina, and I. B. Khaibullin, Vysokochist. Veshchestva 3, 45 (1993).Google Scholar
  16. 16.
    V. Yu. Petukhov, V. A. Zhikharev, V. A. Makovskii, et al., Poverkhnost 4, 24 (1995).Google Scholar
  17. 17.
    V. Yu. Petukhov, M. I. Ibragimova, N. R. Khabibullina, et al., Vysokomol. Soedin., Ser. A 43, 1973 (2001).Google Scholar
  18. 18.
    V. Petukhov, V. Zhikharev, M. Ibragimova, et al., Solid State Commun. 97, 361 (1996).CrossRefGoogle Scholar
  19. 19.
    V. V. Bazarov, V. Yu. Petukhov, V. A. Zhikharev, and I. B. Khaibullin, Mater. Res. Soc. Symp. Proc. 388, 417 (1995).Google Scholar
  20. 20.
    R. I. Khaibullin, Yu. N. Osin, A. L. Stepanov, and I. B. Khaibullin, Vacuum 51, 289 (1998).CrossRefGoogle Scholar
  21. 21.
    R. I. Khaibullin, Yu. N. Osin, A. L. Stepanov, and I. B. Khaibullin, Nucl. Instrum. Methods Phys. Res. B 148, 1023 (1999).CrossRefADSGoogle Scholar
  22. 22.
    R. I. Khaibullin, V. A. Zhikharev, Yu. N. Osin, et al., Nucl. Instrum. Methods Phys. Res. B 166–167, 897 (2000).Google Scholar
  23. 23.
    B. Z. Rameev, B. Aktas, R. I. Khaibullin, et al., Vacuum 58, 551 (2000).CrossRefGoogle Scholar
  24. 24.
    A. L. Stepanov, R. I. Khaibullin, S. N. Abdullin, et al., Mater. Res. Soc. Symp. Proc. 392, 161 (1994).Google Scholar
  25. 25.
    A. L. Stepanov, R. I. Khaibullin, S. N. Abdullin, et al., Inst. Phys. Conf. Ser. 147, 357 (1995).Google Scholar
  26. 26.
    S. N. Abdullin, A. L. Stepanov, R. I. Khaibullin, et al., Fiz. Tverd. Tela (St. Petersburg) 38, 2574 (1996) [Phys. Solid State 38, 1412 (1996)].Google Scholar
  27. 27.
    S. N. Abdullin, A. L. Stepanov, R. I. Khaibullin, and I. B. Khaibullin, RF Patent No. 2,096,835 (1996).Google Scholar
  28. 28.
    S. N. Abdullin, A. L. Stepanov, Yu. N. Osin, et al., Surf. Coat. Technol. 106, 214 (1998).CrossRefGoogle Scholar
  29. 29.
    R. I. Khaibullin, S. N. Abdullin, A. L. Stepanov, et al., Pis’ma Zh. Tekh. Fiz. 22(3), 48 (1996) [Tech. Phys. Lett. 22, 112 (1996)].Google Scholar
  30. 30.
    I. B. Khaibullin, R. I. Khaibullin, S. N. Abdullin, et al., Nucl. Instrum. Methods Phys. Res. B 127–128, 685 (1997).Google Scholar
  31. 31.
    K. Yoshida and M. Iwaki, Nucl. Instrum. Methods Phys. Res. B 19–20, 878 (1987).Google Scholar
  32. 32.
    T. Kobayashi, T. Iwata, Y. Doi, and M. Iwaki, Nucl. Instrum. Methods Phys. Res. B 175–177, 548 (2001).Google Scholar
  33. 33.
    Y. Wu, T. Zhang, Y. Zhang, et al., Surf. Coat. Technol. 148, 221 (2001).Google Scholar
  34. 34.
    A. L. Stepanov, S. N. Abdullin, R. I. Khaibullin, et al., Proc. R. Microsc. Soc. 29, 226 (1994).Google Scholar
  35. 35.
    A. L. Stepanov, S. N. Abdullin, V. Yu. Petukhov, et al., Philos. Mag. B 80, 23 (2000).Google Scholar
  36. 36.
    A. L. Stepanov, V. N. Popok, I. B. Khaibullin, and U. Kreibig, Nucl. Instrum. Methods Phys. Res. B 191, 473 (2002).ADSGoogle Scholar
  37. 37.
    Y. Wu, T. Zhang, A. Liu, et al., Surf. Coat. Technol. 157, 262 (2002).Google Scholar
  38. 38.
    A. L. Stepanov, R. I. Khaibullin, and I. B. Khaibullin, Philos. Mag. Lett. 77, 261 (1998).Google Scholar
  39. 39.
    A. L. Stepanov, S. N. Abdullin, R. I. Khaibullin, et al., Mater. Res. Soc. Symp. Proc. 392, 267 (1995).Google Scholar
  40. 40.
    G. R. Rao, K. Monar, E. H. Lee, and J. R. Treglio, Surf. Coat. Technol. 64, 69 (1994).Google Scholar
  41. 41.
    G. Mie, Ann. Phys. (Leipzig) 25, 377 (1908).zbMATHGoogle Scholar
  42. 42.
    M. A. Khashan and A. Y. Nassif, Opt. Commun. 188, 129 (2001).CrossRefADSGoogle Scholar
  43. 43.
    M. Born and E. Wolf, Principles of Optics (Pergamon Press, Oxford, 1969; Nauka, Moscow, 1973).Google Scholar
  44. 44.
    V. B. Odzhaev, I. P. Kozlov, V. N. Popok, and D. V. Sviridov, Ion Implantation into Polymers (Belarusk. Gos. Univ., Minsk, 1998).Google Scholar
  45. 45.
    A. L. Stepanov, V. A. Zhikharev, and I. B. Khaibullin, Fiz. Tverd. Tela (St. Petersburg) 43, 733 (2001) [Phys. Solid State 43, 766 (2001)].Google Scholar
  46. 46.
    S. Deying, Y. Saito, and S. Suganomata, Jpn. J. Appl. Phys. 33, L966 (1994).CrossRefGoogle Scholar
  47. 47.
    A. L. Stepanov and D. E. Hole, Recent Res. Development Appl. Phys. 5, 1 (2002).Google Scholar
  48. 48.
    W. Scheunemann and H. Jäger, Z. Phys. 265, 441 (1973).Google Scholar
  49. 49.
    C. F. Bohren and D. R. Huffman, Absorption and Scattering of Light by Small Particles (Wiley, New York, 1983; Mir, Moscow, 1986).Google Scholar
  50. 50.
    M. Quinten, Z. Phys. B 101, 211 (1996).CrossRefGoogle Scholar
  51. 51.
    P. B. Johnson and R. W. Christy, Phys. Rev. B 6, 4370 (1972).ADSGoogle Scholar
  52. 52.
    U. Kreibig, J. Phys. F 4, 999 (1974).CrossRefADSGoogle Scholar
  53. 53.
    A. P. Prishivalko and A. F. Sinyuk, Opt. Spektrosk. 79, 139 (1995) [Opt. Spectrosc. 79, 128 (1995)].Google Scholar
  54. 54.
    A. L. Stepanov, Opt. Spektrosk. 91, 868 (2001) [Opt. Spectrosc. 91, 815 (2001)].Google Scholar
  55. 55.
    U. Kreibig, G. Bour, A. Hilger, and M. Gartz, Phys. Status Solidi A 175, 351 (1999).ADSGoogle Scholar
  56. 56.
    D. V. Sviridov, Usp. Khim. 71, 1 (2002).Google Scholar
  57. 57.
    B. Pignataro, M. E. Fragala, and O. Puglisi, Nucl. Instrum. Methods Phys. Res. B 131, 141 (1997).CrossRefADSGoogle Scholar
  58. 58.
    E. D. Palik, Handbook of Optical Constants of Solids (Academic, London, 1997).Google Scholar
  59. 59.
    G. R. Rao, Z. L. Wang, and E. H. Lee, J. Mater. Res. 8, 927 (1993).ADSGoogle Scholar
  60. 60.
    A. Aden and M. Kerker, J. Appl. Phys. 22, 1242 (1951).MathSciNetGoogle Scholar
  61. 61.
    J. Sinzig, U. Radtke, M. Quinten, and U. Kreibig, Z. Phys. D 26, 242 (1993).CrossRefGoogle Scholar
  62. 62.
    J. Sinzig and M. Quinten, Appl. Phys. A 58, 157 (1994).CrossRefGoogle Scholar
  63. 63.
    H. Wang, S. P. Wong, W. Y. Cheung, et al., J. Appl. Phys. 88, 2063 (2000).ADSGoogle Scholar
  64. 64.
    V. I. Ivanov-Omskii, A. V. Tolmatchev, and S. G. Yastrebov, Philos. Mag. B 73, 715 (1996).Google Scholar
  65. 65.
    V. I. Ivanov-Omskii, V. I. Siklitskii, and S. G. Yastrebov, Fiz. Tverd. Tela (St. Petersburg) 40, 568 (1998) [Phys. Solid State 40, 524 (1998)].Google Scholar
  66. 66.
    T. N. Vasilevskaya, S. G. Yastrebov, N. S. Andreev, et al., Fiz. Tverd. Tela (St. Petersburg) 41, 2088 (1999) [Phys. Solid State 41, 1918 (1999)].Google Scholar
  67. 67.
    H. Biederman, Z. Chmel, A. Fejfar, et al., Vacuum 40, 377 (1990).Google Scholar
  68. 68.
    O. Stenzel, H. Kupfer, T. Pfeifer, et al., Opt. Mater. 15, 159 (2000).CrossRefADSGoogle Scholar
  69. 69.
    U. Kreibig, Handbook of Optical Properties, Vol. 2: Optics of Small Particles, Interfaces, and Surfaces, Ed. by R. E. Hummel and P. Wissmann (CRC, London, 1997).Google Scholar
  70. 70.
    J. Hölzl, F. Schulte, and H. Wagner, Solid Surface Physics (Springer, Berlin, 1979).Google Scholar
  71. 71.
    U. Kreibig, M. Gartz, and A. Hilger, Ber. Bunsenges. Phys. Chem. 101, 1593 (1997).Google Scholar

Copyright information

© MAIK "Nauka/Interperiodica" 2004

Authors and Affiliations

  • A. L. Stepanov
    • 1
  1. 1.Kazan Physicotechnical InstituteRussian Academy of SciencesKazan

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