Fluorination of the cubic and hexagonal C60 modifications by crystalline manganese trifluoride
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This paper reports on a comparative study of the solid-state fluorination of the cubic and hexagonal fullerene C60 modifications by crystalline manganese trifluoride. It is shown that the variation of the fullerene crystal structure does not noticeably affect the composition of the fluorination products. The enthalpy and entropy of sublimation of the C60 hexagonal phase are experimentally determined for the first time.