Selective electrochemical oxidation of ammonia provides an ideal pathway to synthesize hydrazine, but this process is outcompeted by a more favourable overoxidation to N2. A molecular ruthenium catalyst has now flipped the script, circumventing the thermodynamic challenges to selectively generate hydrazine.
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Garrido-Barros, P., Funes-Ardoiz, I. Defying thermodynamics to synthetize hydrazine. Nat Catal 6, 868–869 (2023). https://doi.org/10.1038/s41929-023-01033-z
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DOI: https://doi.org/10.1038/s41929-023-01033-z
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