Atomically dispersed and nitrogen-coordinated single iron site catalysts hold great promise to replace platinum for proton-exchange membrane fuel cells, but they suffer from significant performance loss. Now, solving the conundrum to distinguish durable and non-durable FeN4 active sites can guide high-performance catalyst design.
References
Wang, X. X., Swihart, M. T. & Wu, G. Nat. Catal. 2, 578–589 (2019).
Wu, G., More, K. L., Johnston, C. M. & Zelenay, P. Science 332, 443–447 (2011).
Zhang, H. et al. Energy Environ. Sci. 12, 2548–2558 (2019).
Zhang, H. et al. J. Am. Chem. Soc. 139, 14143–14149 (2017).
He, Y., Liu, S., Priest, C., Shi, Q. & Wu, G. Chem. Soc. Rev. 49, 3484–3524 (2020).
Shao, Y., Dodelet, J.-P., Wu, G. & Zelenayet, P. Adv. Mater. 31, 1807615 (2019).
Jia, Q., Liu, E., Jiao, L., Pann, S. & Mukerjee, S. Adv. Mater. 31, 1805157 (2018).
Li, J. et al. Nat. Catal. https://doi.org/10.1038/s41929-020-00545-2 (2020).
Wang, X. X., Prabhakaran, V., He, Y., Shao, Y. & Wu, G. Adv. Mater. 31, 1805126 (2019).
He, Y. et al. Adv. Mater. 32, 2003577 (2020).
Shi, Q. et al. Mater. Today 37, 93–111 (2020).
Zhu, Y. et al. Adv. Energy Mater. 10, 1902844 (2020).
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Competing interests
The authors declare no competing interests.
Rights and permissions
About this article
Cite this article
Liu, S., Shi, Q. & Wu, G. Solving the activity–stability trade-off riddle. Nat Catal 4, 6–7 (2021). https://doi.org/10.1038/s41929-020-00567-w
Published:
Issue Date:
DOI: https://doi.org/10.1038/s41929-020-00567-w
- Springer Nature Limited
This article is cited by
-
Two-electron redox chemistry via single-atom catalyst for reversible zinc–air batteries
Nature Sustainability (2024)
-
Tuning the thermal activation atmosphere breaks the activity–stability trade-off of Fe–N–C oxygen reduction fuel cell catalysts
Nature Catalysis (2023)
-
Atomically dispersed iron sites with a nitrogen–carbon coating as highly active and durable oxygen reduction catalysts for fuel cells
Nature Energy (2022)