Enhancing the oxygen exchange rate at the surface of oxides through rational design has long been a key goal of researchers pursuing sustainable energy solutions. Now, a simple infiltration method reveals that reaction rates on porous mixed-conducting oxides scale with the acidity of the infiltrate and can be tuned by orders of magnitude.
References
Choudhury, A., Chandra, H. & Arora, A. Renew. Sust. Energ. Rev. 20, 430–442 (2013).
Jiang, Z. Y., Xia, C. R. & Chen, F. L. Electrochim. Acta 55, 3595–3605 (2010).
Adler, S. B. Chem. Rev. 104, 4791–4843 (2004).
Hu, B. B. & Xia, C. R. Asia-Pac. J. Chem. Eng. 11, 327–337 (2016).
Nicollet, C. T. et al. Nat. Catal. https://doi.org/10.1038/s41929-020-00520-x (2020).
González-Cobos, J. & de Lucas-Consuegra, A. Catalysts 6, 15 (2016).
Onn, T. M., Küngas, R., Fornasiero, P., Huang, K. & Gorte, R. J. Inorganics 6, 1–20 (2018).
Schaube, M., Merkle, R. & Maier, J. J. Mater. Chem. A 7, 21854–21866 (2019).
Trovarelli, A. & Llorca, J. ACS Catal. 7, 4716–4735 (2017).
Usiskin, R. E., Maruyama, S., Kucharczyk, C. J., Takeuchi, I. & Haile, S. M. J. Mater. Chem. A 3, 19330–19345 (2015).
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Competing interests
The author declares no competing interests.
Rights and permissions
About this article
Cite this article
Haile, S.M. Accelerating oxygen surface exchange. Nat Catal 3, 863–864 (2020). https://doi.org/10.1038/s41929-020-00537-2
Published:
Issue Date:
DOI: https://doi.org/10.1038/s41929-020-00537-2
- Springer Nature Limited