Tensile strain of a solid surface can result in either strengthening or weakening of bonds with adsorbates. Adsorption energies of different adsorbate/site combinations may be shifted in different directions — a striking violation of the Brønsted–Evans–Polanyi relation.
References
Mavrikakis, M., Hammer, B. & Norskov, J. K. Phys. Rev. Lett. 81, 2819–2822 (1998).
Gorsky, W. Physikal. Z. Sowjetunion 8, 457–471 (1935).
Larché, F. & Cahn, J. W. Acta Metall. 21, 1051–1063 (1973).
Fratzl, P., Penrose, O. & Lebowitz, J. L. J. Stat. Phys. 95, 1429–1503 (1999).
Khorshidi, A., Violet, J., Hashemi, J. & Peterson, A. A. Nat. Catal. https://doi.org/10.1038/s41929-018-0042-4 (2018).
Deng, Q., Smetanin, M. & Weissmüller, J. J. Catal. 309, 351–361 (2014).
Kibler, L. A., El-Aziz, A. M., Hoyer, R. & Kolb, D. M. Angew. Chem. Int. Ed. 44, 2080–2084 (2005).
Weissmüller, J., Viswanath, R. N., Kibler, L. A. & Kolb, D. M. Phys. Chem. Chem. Phys. 13, 2114–2117 (2011).
Deng, Q., Gopal, V. & Weissmüller, J. Angew. Chem. Int. Ed. 127, 13173–13177 (2015).
Stafford, G. R. & Bertocci, U. J. Phys. Chem. C 113, 261–268 (2009).
Gokhshtein, A. Y. Doklady Akademii Nauk SSSR 187, 601–604 (1969).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Weissmüller, J. Mechanochemistry breaks with expectations. Nat Catal 1, 238–239 (2018). https://doi.org/10.1038/s41929-018-0061-1
Published:
Issue Date:
DOI: https://doi.org/10.1038/s41929-018-0061-1
- Springer Nature Limited
This article is cited by
-
Understanding mechanical modulation of electrocatalytic reaction with an electrical circuit model
Acta Mechanica Sinica (2024)