An important but difficult separation, the removal of carbon monoxide from humid gas mixtures comprising oxygen, nitrogen and hydrocarbons, is addressed by exploiting Cu(I) coordination chemistry and framework flexibility.
References
Sholl, D. S. & Lively, R. P. Nature 532, 435–437 (2016).
Zhang, X.-W. et al. Nat. Mater. https://doi.org/10.1038/s41563-023-01729-4 (2023).
Feynman, R. P. Caltech Eng. Sci. 23, 22–36 (1960).
Maddox, J. S. Nature 335, 201 (1988).
Hoskins, B. F. & Robson, R. J. Am. Chem. Soc. 111, 5962–5964 (1989).
Moulton, B. & Zaworotko, M. J. Chem. Rev. 101, 1629–1658 (2001).
Furukawa, H. et al. Science 341, 1230444 (2013).
Groom, C. R. et al. Acta Cryst. B72, 171–179 (2016).
Zhuo, L.-L. et al. Angew. Chem. Int. Ed. 61, e202204967 (2022).
LeBlanc, F. et al. Compt. Rend. 30, 483–485 (1850).
MacDonald, T. M. et al. Nature 519, 303–308 (2015).
He, T. et al. Nat. Mater. 21, 689–695 (2022).
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The author has patents issued or pending on direct air capture and atmospheric water harvesting in MOFs and related porous materials.
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Zaworotko, M.J. Engineering porous crystals to do different things. Nat. Mater. 23, 39–40 (2024). https://doi.org/10.1038/s41563-023-01749-0
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DOI: https://doi.org/10.1038/s41563-023-01749-0
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