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Nitrogen electroreduction

Beyond lithium for sustainable ammonia synthesis

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Using an electrochemical continuous flow cell, nitrogen reduction to ammonia is rigorously demonstrated through a calcium-mediated approach.

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Fig. 1: Proposed mechanism for continuous electrochemical ammonia synthesis via Ca-NRR.

References

  1. Smith, C., Hill, A. K. & Torrente-Murciano, L. Energy Environ. Sci. 13, 331–344 (2020).

    Article  Google Scholar 

  2. Xu, J. & Froment, G. F. AIChE J. 35, 88–96 (1989).

    Article  CAS  Google Scholar 

  3. Guo, W., Zhang, K., Liang, Z., Zou, R. & Xu, Q. Chem. Soc. Rev. 48, 5658–5716 (2019).

    Article  CAS  Google Scholar 

  4. Kyriakou, V., Garagounis, I., Vourros, A., Vasileiou, E. & Stoukides, M. Joule 4, 142–158 (2019).

    Article  Google Scholar 

  5. Comer, B. M. et al. Joule 3, 1578–1605 (2019).

    Article  CAS  Google Scholar 

  6. Xianbiao, F. et al. Nat. Mater. https://doi.org/10.1038/s41563-023-01702-1 (2023).

    Article  Google Scholar 

  7. Fu, X. et al. Science 379, 707–712 (2023).

    Article  CAS  Google Scholar 

  8. Steinberg, K. et al. Nat. Energy 8, 138–148 (2023).

    Article  CAS  Google Scholar 

  9. Li, S. et al. Joule 6, 2083–2101 (2022).

    Article  CAS  Google Scholar 

  10. McShane, E. J. et al. ACS Energy Lett. 8, 4024–4032 (2023).

    Article  CAS  Google Scholar 

  11. Aurbach, D., Skaletsky, R. & Gofer, Y. J. Electrochem. Soc. 138, 3536–3545 (1991).

    Article  CAS  Google Scholar 

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Correspondence to Karthish Manthiram.

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Yusov, M.A., Manthiram, K. Beyond lithium for sustainable ammonia synthesis. Nat. Mater. 23, 31–32 (2024). https://doi.org/10.1038/s41563-023-01747-2

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