Skip to main content
SpringerLink
Log in

A criterion for evaluating Li-dendrite-suppression capability for the design of solid electrolyte interphases

  • Research Briefing
  • Published:

From Nature Energy

View current issue Submit your manuscript

The critical interphase overpotential (CIOP) represents the capability of the interphase on solid-state electrolyte surfaces to suppress Li-dendrite penetration. An interphase with a high CIOP is shown to enable an all-solid-state Li-metal battery to operate at high current and high capacity.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1: CIOP concept for the development of a Li-dendrite-free interlayer.

References

  1. Porz, L. et al. Mechanism of lithium metal penetration through inorganic solid electrolytes. Adv. Energy Mater. 7, 1701003 (2017). This paper reports that a small overpotential can lead to SSE fracture caused by Li plating.

    Article  Google Scholar 

  2. Kasemchainan, J. et al. Critical stripping current leads to dendrite formation on plating in lithium anode solid electrolyte cells. Nat. Mater. 18, 1105–1111 (2019). This paper shows that void formation at the Li–SSE interface leads to Li-dendrite growth.

    Article  Google Scholar 

  3. Park, R. J. Y. et al. Semi-solid alkali metal electrodes enabling high critical current densities in solid electrolyte batteries. Nat. Energy 6, 314–322 (2021). This paper reports that Li-dendrite penetration can be suppressed by avoiding the formation of voids at the Li–SSE interface using Na–K liquid metal.

    Article  Google Scholar 

  4. Friedrichs, P., Burte, E. P. & Schörner, R. Dielectric strength of thermal oxides on 6H‐SiC and 4H‐SiC. Appl. Phys. Lett. 65, 1665–1667 (1994). This paper investigates the dielectric strength of the oxide layer formed on SiC.

    Article  Google Scholar 

Download references

Additional information

Publisher’s note Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

This is a summary of: Wan, H. et al. Critical interphase overpotential as a lithium dendrite-suppression criterion for all-solid-state lithium battery design. Nat. Energy https://doi.org/10.1038/s41560-023-01231-w (2023).

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

A criterion for evaluating Li-dendrite-suppression capability for the design of solid electrolyte interphases. Nat Energy 8, 431–432 (2023). https://doi.org/10.1038/s41560-023-01246-3

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1038/s41560-023-01246-3

  • Springer Nature Limited

Search

Navigation