It is now almost 50 years since the first rechargeable lithium batteries, based on the reversible intercalation of lithium into layered structured titanium disulfide, were conceived. They were the precursor to the structurally related layered oxides that now dominate energy storage for electronics, the grid and vehicles.
References
Gamble, F. R. et al. Science 174, 493–497 (1971).
Whittingham, M. S. Prog. Solid State Chem. 12, 41–99 (1978).
Thompson, A. H. Phys. Rev. Lett. 35, 1786–1789 (1975).
Dines, M. B. Method for lithiating metal chalcogenides and intercalated products thereof. US patent 3,933,688 (1974).
Whittingham, M. S. Chalcogenide battery. US patent 4,009,052 (1973).
Whittingham, M. S. Chalcogenide battery. UK patent 1,468,416 (1973).
Whittingham, M. S. Science 192, 1126–1127 (1976).
Rao, B. M. L., Francis, R. W. & Christopher, H. A. J. Electrochem. Soc. 124, 1490–1492 (1977).
Thorp, A. J., Clamp, F., Feld, R., Page-Gibson, J. E. & Archer, K. Process for the production of titanium disulfide. US patent 4,137,297 (1977).
Panster, P., Mueller, R. & Kleinschmit, P. Preparing titanium disulfide for use in batteries. US patent 4,772,457 (1986).
Chianelli, R. R., Scanlon, J. C. & Rao, B. M. L. J. Electrochem. Soc. 125, 1563–1566 (1978).
Thompson, A. H. Phys. Rev. Lett. 40, 1511–1514 (1978).
Whittingham, M. S. Mater. Res. Bull. 13, 959–965 (1978).
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Whittingham, M.S. Lithium titanium disulfide cathodes. Nat Energy 6, 214 (2021). https://doi.org/10.1038/s41560-020-00765-7
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DOI: https://doi.org/10.1038/s41560-020-00765-7
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