A century-old puzzle on the apparent contradiction that some materials disorder as they are cooled gains universality following new observations of closed-loop phase behaviour in a block-copolymer system.
References
Hudson, C.S. Z. Phys. Chem. 47, 113–115 (1904).
Ryu, D.Y., Jeong, U., Kim, J.K. & Russell, T.P. Nature Mater. 2, 114–117, (2002).
Leibler, L. Macromolecules 13, 1602–1617 (1980).
Bernstein, R.E., Cruz, C.A., Paul, D.R. & Barlow, J.W. Macromolecules 10, 681–686 (1977).
Russell, T.P., Karis, T.E., Gallot, Y. & Mayes, A.M. Nature 368, 729–731 (1994).
Hirschfelder, J., Stevenson, D. & Eyring, H. J. Chem. Phys. 5, 896–912 (1937).
McMaster, L.P. Macromolecules 6, 760–773 (1973).
Jackson, G. Mol. Phys. 72, 1365–1385 (1991).
Walker, J.S. & Vause, C.A. Sci. Am. 256, 90–97 (1987).
Ruzette, A.-V.G. et al. Macromolecules 31, 8509–8516 (1998).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Ruzette, AV. Copolymers close the loop. Nature Mater 1, 85–87 (2002). https://doi.org/10.1038/nmat739
Issue Date:
DOI: https://doi.org/10.1038/nmat739
- Springer Nature Limited