Electrically tunable materials are used to construct switches and memory devices. Applying an electric field within a specific temperature range to cyanometallate complexes triggers their charge-transfer phase transition, altering their optical and magnetic properties.
References
Potember, R. S., Poehler, T. O. & Cowan, D. O. Apply. Phys. Lett. 34, 405–407 (1979).
Sawano, F. et al. Nature 437, 522–524 (2005).
Mahfoud, T. et al. J. Am. Chem. Soc. 131, 15049–15054 (2009).
Verdaguer, M. et al. Coord. Chem. Rev. 190–192, 1023–1047 (1999).
Koshihara, S., Tokura, Y., Takeda, K. & Koda, T. Phys. Rev. Lett. 68, 1148–1151 (1992).
Ohkoshi, S., Tokoro, H. & Hashimoto, K. Coord. Chem. Rev. 249, 1830–1840 (2005).
Bonhommeau, S. et al. Angew. Chem. Int. Ed. 46, 4069–4073 (2005).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Sato, O. An electric effect. Nature Chem 2, 10–11 (2010). https://doi.org/10.1038/nchem.497
Issue Date:
DOI: https://doi.org/10.1038/nchem.497
- Springer Nature Limited