Research efforts related to the Hofmeister series of salt ions have waxed and waned during its long and storied history. The past few decades have, however, witnessed a renaissance in its study, and the importance of the related solvation science is becoming ever more apparent.
References
Hofmeister, F. Arch. Exp. Pathol. Pharmakol. (Leipzig) 24, 247–260 (1888).
Hofmeister, F. Arch. Exp. Pathol. Pharmakol. (Leipzig) 25, 1–30 (1888).
Cox, W. M. & Wolfenden, J. H. Proc. R. Soc. London A 145, 475–488 (1934).
Gurney, R. W. Ionic Processes in Solution (McGraw-Hill, 1953).
Marcus, Y. Chem. Rev. 109, 1346–1370 (2009).
Hribar, B., Southall, N. T., Vlachy, V. & Dill, K. A. J. Am. Chem. Soc. 124, 12302–12311 (2002).
Thomas, A. S. & Elcock, A. H. J. Am. Chem. Soc. 129, 14887–14898 (2007).
Omta, A. W., Kropman, M. F., Woutersen, S. & Bakker, H. J. Science 301, 347–349 (2003).
Funkner, S. et al. J. Am. Chem. Soc. 134, 1030–1035 (2012).
Traube, J. J. Phys. Chem. 14, 452–470 (1910).
Rieskautt, M. M. & Ducruix, A. F. J. Biol. Chem. 264, 745–748 (1989).
Zhang, Y. J. & Cremer, P. S. Proc. Natl Acad. Sci. USA 106, 15249–15253 (2009).
Bello, J. & Bello, H. R. Nature 190, 440–441 (1961).
Bello, J. & Bello, H. R. Nature 194, 681–682 (1962).
Robinson, D. R. & Jencks, W. P. J. Am. Chem. Soc. 87, 2470–2479 (1965).
Nandi, P. K. & Robinson, D. R. J. Am. Chem. Soc. 94, 1299–1308 (1972).
Arakawa, T. & Timasheff, S. N. Biochemistry 21, 6545–6552 (1982).
Von Hippel, P., Peticola, V., Schack, L. & Karlson, L. Biochemistry 12, 1256–1264 (1973).
Paterova, J. et al. J. Phys. Chem. B 117, 8150–8158 (2013).
Cacace, M. G., Landau, E. M. & Ramsden, J. J. Q. Rev. Biophys. 30, 241–277 (1997).
Collins, K. D. & Washabaugh, M. W. Q. Rev. Biophys. 18, 323–422 (1985).
Kunz, W., Lo Nostro, P. & Ninham, B. W. Curr. Opin. Colloid Interf. Sci. 9, 1–18 (2004).
Kunz, W., Henle, J. & Ninham, B. W. Curr. Opin. Colloid Interf. Sci. 9, 19–37 (2004).
Wilson, E. K. Chem. Eng. News 85, 47–49 (26 November 2007).
Lo Nostro, P. & Ninham, B. W. Chem. Rev. 112, 2286–2322 (2012).
Bostrom, M., Williams. D. R. M. & Ninham, B. W. Curr. Opin. Colloid Interf. Sci. 9, 48–52 (2004).
Wilson, E. K. Chem. Eng. News 90, 42–43 (16 July 2012).
Tobias, D. J. & Hemminger, J. C. Science 319, 1197–1198 (2008).
Nandi, P. K. & Robinson, D. R. J. Am. Chem. Soc. 94, 1308–1315 (1972).
Baldwin, R. L. Biophys. J. 71, 2056–2063 (1996).
Street, T. O., Bolen, D. W. & Rose, G. D. Proc. Natl Acad. Sci. USA 103, 13997–14002 (2006).
Pegram, L. M. & Record, M. T. J. Phys. Chem. B 112, 9428–9436 (2008).
Kalcher, I., Horinek, D., Netz, R. R. & Dzubiella, J. J. Phys. Condens. Matter 21, 424108 (2009).
Rembert, K. B. et al. J. Am. Chem. Soc. 134, 10039–10046 (2012).
Okur, H. I., Kherb, J. & Cremer, P. S. J. Am. Chem. Soc. 135, 5062–5067 (2013).
Heyda, J., Vincent, J. C., Tobias, D. J., Dzubiella, J. & Jungwirth, P. J. Phys. Chem. B 114, 1213–1220 (2010).
Algaer, E. A. & van der Vegt, N. F. A. J. Phys. Chem. B 115, 13781–13787 (2011).
Collins, K. D. Biophys. J. 72, 65–76 (1997).
Collins, K. D., Neilson, G. W. & Enderby, J. E. Biophys. Chem. 128, 95–104 (2007).
Hess, B. & van der Vegt, N. F. A. Proc. Natl Acad. Sci. USA 106, 13296–13300 (2009).
Heyda, J., Hrobarik, T. & Jungwirth, P. J. Phys. Chem. A 113, 1969–1975 (2009).
Aziz, E. F. et al. J. Phys. Chem. B 112, 12567–12570 (2008).
Uejio, J. S. et al. Proc. Natl Acad. Sci. USA 105, 6809–6812 (2008).
Vrbka, L., Vondrasek, J., Jagoda-Cwiklik, B., Vacha, R. & Jungwirth, P. Proc. Natl Acad. Sci. USA 103, 15440–15444 (2006).
Heyda, J. et al. Phys. Chem. Chem. Phys. 11, 7599–7604 (2009).
Friedman, R. J. Phys. Chem. B 115, 9213–9223 (2011).
Horinek, D. & Moeser, B. J. Phys. Chem. B 118, 107–114 (2014).
Schneider, C. P, Shukla, D. & Trout, B. L. J. Phys. Chem. B 115, 7447–7458 (2011).
Tanford, C. Physical Chemistry of Macromolecules (Wiley, 1961).
Mason, P. E. et al. J. Phys. Chem. B 113, 3227–3234 (2009).
Dempsey, C. E., Mason, P. E. & Jungwirth, P. J. Am. Chem. Soc. 133, 7300–7303 (2011).
Ball, P. Faraday Discuss. 160, 405–414 (2013).
Author information
Authors and Affiliations
Corresponding authors
Rights and permissions
About this article
Cite this article
Jungwirth, P., Cremer, P. Beyond Hofmeister. Nature Chem 6, 261–263 (2014). https://doi.org/10.1038/nchem.1899
Published:
Issue Date:
DOI: https://doi.org/10.1038/nchem.1899
- Springer Nature Limited
This article is cited by
-
Interactions between the protein barnase and co-solutes studied by NMR
Communications Chemistry (2024)
-
Solvent effects in anion recognition
Nature Reviews Chemistry (2024)
-
Sustainable 3D printing by reversible salting-out effects with aqueous salt solutions
Nature Communications (2024)
-
Morphogenesis of starfish polymersomes
Nature Communications (2023)
-
Solubilities of Amino Acids in the Presence of Chaotropic Anions
Journal of Solution Chemistry (2023)