Covalently bonding groups to the walls of carbon nanotubes has been previously observed to quench their photoluminescence. Now, it has been shown that, if you get the chemistry just right, their photoluminescence can in fact be significantly brightened by introducing defects through functionalization.
References
William, D., Callister, J. & Rethwisch, D. G. Materials Science and Engineering: An Introduction. 8th edn (Wiley, 2010).
Piao, Y. et al. Nature Chem. 5, 840–845 10.1038/nchem.1711(2013).
Welsher, K., Sherlock, S. P. & Dai, H. Proc. Natl Acad. Sci. 108, 8943–8948 (2011).
Barone, P. W., Baik, S., Heller, D. A. & Strano, M. S. Nature Mater. 4, 86–92 (2005).
Avouris, P., Freitag, M. & Perebeinos, V. Nature Photon. 2, 341–350 (2008).
Crochet, J., Clemens, M. & Hertel, T. J. Am. Chem. Soc. 129, 8058–8059 (2007).
Scholes, G. D. et al. J. Phys. Chem. C 111, 11139–11149 (2007).
Cognet, L. et al. Science 316, 1465–1468 (2007).
Miyauchi, Y. et al. Nature Photon. 7, 715–719 (2013).
Ghosh, S., Bachilo, S. M., Simonette, R. A., Beckingham, K. M. & Weisman, R. B. Science 330, 1656–1659 (2010).
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Wang, Q., Strano, M. A bright future for defects. Nature Chem 5, 812–813 (2013). https://doi.org/10.1038/nchem.1768
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DOI: https://doi.org/10.1038/nchem.1768
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