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Metal-organic frameworks

A porous maze

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Observing the diffusion of guest molecules in large single crystals of a metal-organic framework reveals surprising insights into the blockage of the channels at the material's surface and the role of defects within its bulk.

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Figure 1: Illustration of three possible scenarios for molecules diffusing through a crystal with parallel one-dimensional pores.

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Correspondence to David S Sholl.

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Sholl, D. A porous maze. Nature Chem 3, 429–430 (2011). https://doi.org/10.1038/nchem.1054

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