The report of a light-activated catalyst that dictates the three-dimensional shape — the stereochemistry — of molecules formed in an organic reaction suggests a new strategy for controlling such reactions using visible light. See Letter p.100
References
Huo, H. et al. Nature 515, 100–103 (2014).
Schultz, D. M. & Yoon, T. P. Science 343, 1239176 (2014).
Gong, L., Wenzel, M. & Meggers, E. Acc. Chem. Rev. 46, 2635–2644 (2013).
Chen, L.-A. et al. J. Am. Chem. Soc. 135, 10598–10601 (2013).
Huo, H., Fu, C., Harms, K. & Meggers, E. J. Am. Chem. Soc. 136, 2990–2993 (2014).
Inoue, Y. Chem. Rev. 92, 741–770 (1992).
Nicewicz, D. A. & MacMillan, D. W. C. Science 322, 77–80 (2008).
Du, J., Skubi, K. L., Schultz, D. M. & Yoon, T. P. Science 344, 392–396 (2014).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Skubi, K., Yoon, T. Shape control in reactions with light. Nature 515, 45–46 (2014). https://doi.org/10.1038/515045a
Published:
Issue Date:
DOI: https://doi.org/10.1038/515045a
- Springer Nature Limited
This article is cited by
-
In situ observation of a stepwise [2 + 2] photocycloaddition process using fluorescence spectroscopy
Nature Communications (2023)
-
Controllable multiple-step configuration transformations in a thermal/photoinduced reaction
Nature Communications (2022)