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Not just any old anion

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Unlike its neighbours on the right-hand side of the periodic table, boron barely forms an anion. A new trick has been established that allows it to do so, enabling a highly unusual complex to be prepared.

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Figure 1: A stable anion of borole.

References

  1. de Meijere, A. & Diederich, F. (eds) Metal-Catalyzed Cross-Coupling Reactions 2nd edn (Wiley, 2004).

    Book  Google Scholar 

  2. Eisch, J. J., Galle, J. E. & Kozima, S. J. Am. Chem. Soc. 108, 379–385 (1986).

    Article  CAS  Google Scholar 

  3. Wakamiya, A., Mishima, K., Ekawa, K. & Yamaguchi, S. Chem. Commun. 579–581 (2008).

  4. Braunschweig, H., Chiu, C.-W., Radacki, K. & Kupfer, T. Angew. Chem. Int. Edn 49, 2041–2044 (2010).

    Article  CAS  Google Scholar 

  5. Parsons, T. D., Self, J. M. & Schaad, L. H. J. Am. Chem. Soc. 89, 3446–3448 (1967).

    Article  CAS  Google Scholar 

  6. Blumenthal, A., Bissinger, P. & Schmidbaur, H. J. Organomet. Chem. 462, 107–110 (1993).

    Article  CAS  Google Scholar 

  7. Imamoto, T. & Hikosaka, T. J. Org. Chem. 59, 6753–6759 (1994).

    Article  CAS  Google Scholar 

  8. Segawa, Y., Yamashita, M. & Nozaki, K. Science 314, 113–115 (2006).

    Article  ADS  CAS  Google Scholar 

  9. Segawa, Y., Suzuki, Y., Yamashita, M. & Nozaki, K. J. Am. Chem. Soc. 130, 16069–16079 (2008).

    Article  CAS  Google Scholar 

  10. Loginov, D. A., Muratov, D. V. & Kudinov, A. R. Russ. Chem. Bull. 57, 1–7 (2008).

    Article  CAS  Google Scholar 

  11. So, C.-W., Watanabe, D., Wakamiya, A. & Yamaguchi, S. Organometallics 27, 3496–3501 (2008).

    Article  CAS  Google Scholar 

  12. Herberich, G. E., Wagner, T. & Marx, H.-W. J. Organomet. Chem. 502, 67–74 (1995).

    Article  CAS  Google Scholar 

  13. Walton, J. C. et al. J. Am. Chem. Soc. 132, 2350–2358 (2010).

    Article  CAS  Google Scholar 

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Nozaki, K. Not just any old anion. Nature 464, 1136–1137 (2010). https://doi.org/10.1038/4641136a

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