Violent criminals are imprisoned to keep them under control. Similarly, incarceration in a molecular jail stops white phosphorus from bursting into flames — but on release, it regains its fiery character.
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References
Mal, P., Breiner, B., Rissanen, K. & Nitschke, J. R. Science 324, 1697–1699 (2009).
Saalfrank, R. W., Hörner, B., Stalke, D. & Salbeck, J. Angew. Chem. Int. Edn 32, 1179–1182 (1993).
Caulder, D. L., Powers, R. E., Parac, T. N. & Raymond, K. N. Angew. Chem. Int. Edn 37, 1840–1843 (1998).
Yoshizawa, M., Klosterman, J. K. & Fujita, M. Angew. Chem. Int. Edn 48, 3418–3438 (2009).
Hou, J.-L., Ajami, D. & Rebek, J. Jr J. Am. Chem. Soc. 130, 7810–7811 (2008).
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Raymond, K. Phosphorus caged. Nature 460, 585–586 (2009). https://doi.org/10.1038/460585a
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DOI: https://doi.org/10.1038/460585a
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