The nature of the boundary between water and oil is crucial to many nanometre-scale assembly processes, including protein folding. But until now, what the interface really looks like remained in dispute.
References
Poynor, A. et al. Phys. Rev. Lett. 97, 266101 (2006).
Mezger, M. et al. Proc. Natl Acad. Sci. USA 103, 18401–18404 (2006).
Giovambattista, N., Debenedetti, P. G. & Rossky, P. J. J. Phys. Chem. C 111, 1323–1332 (2007).
Stillinger, F. H. J. Solut. Chem. 2, 141–158 (1973).
Lum, K., Chandler, D. & Weeks, J. D. J. Phys. Chem. B 103, 4570–4577 (1999).
Chandler, D. Nature 437, 640–647 (2005).
Ball, P. Nature 423 25–26 (2003).
Wallqvist, A. & Berne, B. J. J. Phys. Chem. 99, 2893–2899 (1995).
Zhang, X., Zhu, Y. & Granick, S. Science 295, 663–666 (2002).
Hummer, G., Rasaiah, J. C. & Noworyta, J. P. Nature 414, 188–190 (2001).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Chandler, D. Oil on troubled waters. Nature 445, 831–832 (2007). https://doi.org/10.1038/445831a
Published:
Issue Date:
DOI: https://doi.org/10.1038/445831a
- Springer Nature Limited
This article is cited by
-
Water accelerated self-healing of hydrophobic copolymers
Nature Communications (2020)
-
Collaborative routes to clarifying the murky waters of aqueous supramolecular chemistry
Nature Chemistry (2018)
-
Combining molecular dynamics and lattice Boltzmann simulations: a hierarchical computational protocol for microfluidics
Microfluidics and Nanofluidics (2016)
-
On the cooperative formation of non-hydrogen-bonded water at molecular hydrophobic interfaces
Nature Chemistry (2013)
-
Influence of the size of fixed-rigidity spheres on the structural and energy characteristics of hydrophobic hydration
Russian Chemical Bulletin (2008)