Skip to main content
Log in

Disequilibrium and macrosegregation during solidification of a binary melt

  • Article
  • Published:

From Nature

View current issue Submit your manuscript

Abstract

The crystallization of a liquid mixture in the presence of natural convection is an important problem in geophysics and metallurgy. Simple aqueous solutions may be used as analogue systems to study this process. Both theory and experiment reveal that convective motions in the fluid are important in determining both the rate of solidification and the development of compositional stratification in the solid. Moreover, convection may result in solidification in regions other than near the boundary at which cooling is imposed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Huppert, H. E. & Worster, M. G. Nature 314, 703–707 (1985).

    Article  ADS  CAS  Google Scholar 

  2. Turner, J. S., Huppert, H. E. & Sparks, R. S. J. J. Petrology 27, 397–437 (1986).

    Article  ADS  CAS  Google Scholar 

  3. Flemings, M. C. in Modeling of Casting and Welding Processes (eds Brody, H. D. & Arpelian, D.) 533–548 (The Metallurgical Society of the American Institute of Mining, Metallurgical and Petroleum Engineers, Warrendale, 1981).

    Google Scholar 

  4. Hills, R. N., Loper, D. E. & Roberts, P. H. Q. Jl Mech. appl. Math. 36, 505–539 (1983).

    Article  Google Scholar 

  5. Worster, M. G. J. Fluid Mech. 167, 481–501 (1986).

    Article  ADS  CAS  Google Scholar 

  6. Batchelor, G. K. A. Rev. Fluid Mech. 6, 227–255 (1974).

    Article  ADS  Google Scholar 

  7. Turner, J. S. Buoyancy Effects in Fluids (Cambridge University Press, 1979).

    MATH  Google Scholar 

  8. Kurz, W. & Fisher, D. J. Fundamentals of Solidification (Trans Tech Publications, Aedermannsdorf, 1986).

    Google Scholar 

  9. Flood, S. C. & Hunt, J. D. Appl. Sci. Res. 44, 27–42 (1987).

    Article  CAS  Google Scholar 

  10. Brice, J. C. Crystal Growth Processes (Blackie, Glasgow, 1986).

    Google Scholar 

  11. Brown, R. A. A.I.Ch.E. Jl 34, 881–911 (1988).

    Article  CAS  Google Scholar 

  12. Turcotte, D. L. & Schubert, G. Geodynamics (Wiley, New York, 1982).

    Google Scholar 

  13. Norton, D. & Taylor, H. P. J. Petrology 20, 421–486 (1979).

    Article  ADS  CAS  Google Scholar 

  14. Brandeis, G. & Jaupart, C. Earth planet. Sci. Lett. 77, 345–361 (1986).

    Article  ADS  Google Scholar 

  15. Shirley, D. N. J. Petrology 28, 835–866 (1987).

    Article  ADS  CAS  Google Scholar 

  16. Nilson, R. H. McBirney, A. R. & Baker, B. H. J. Volcan. geotherm. Res. 24, 25–54 (1985).

    Article  ADS  Google Scholar 

  17. Huppert, H. E., Sparks, R. S. J., Wilson, J. R. & Hallworth, M. A. Earth planet. Sci. Lett. 79, 319–328 (1986).

    Article  ADS  Google Scholar 

  18. Huppert, H. E., Sparks, R. S. J., Wilson, J. R., Hallworth, M. A. & Leitch, A. M. in Origins of Igneous Layering (ed. Parsons, I.) 539–568 (Reidel, Dordrecht, 1987).

    Book  Google Scholar 

  19. Roberts, P. H. & Loper, D. E. in Structure and Dynamics of Partially Solidified Systems (ed. Loper, D. E.) 229–290 (Martinus Nijhoff, Dordrecht, 1987).

    Book  Google Scholar 

  20. Abegg, R. Z. phys. Chem. 15, 209–261 (1894).

    Article  CAS  Google Scholar 

  21. Denton, R. A. & Wood, I. R. Int. J. Heat Mass Transf. 22, 1339–1346 (1979).

    Article  ADS  Google Scholar 

  22. Kaye, G. W. C. & Laby, T. H. Tables of Physical and Chemical Constants and Some Mathematical Functions (Longman, London and New York, 1973).

    MATH  Google Scholar 

  23. Vargaftik, N. B. Tables on the Thermodynamic Properties of Liquids and Gases (Wiley, New York, 1975).

    Google Scholar 

  24. Washburn, E. W. (ed.) International Critical Tables of Numerical Data: Physics, Chemistry and Technology (McGraw-Hill, New York and London, 1926).

  25. Weast, R. C. (ed.) CRC Handbook of Chemistry and Physics (Chemical Rubber Co., Cleveland, 1971).

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kerr, R., Woods, A., Worster, M. et al. Disequilibrium and macrosegregation during solidification of a binary melt. Nature 340, 357–362 (1989). https://doi.org/10.1038/340357a0

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1038/340357a0

  • Springer Nature Limited

This article is cited by

Navigation