Skip to main content
Log in

Vitrification of pure liquid water by high pressure jet freezing

  • Article
  • Published:

From Nature

View current issue Submit your manuscript

Abstract

The vitrification of pure liquid water by projecting a thin jet of liquid water at high speed into a liquid cryomedium is reported. The influence of the experimental parameters on the cooling rate and the devitrification of the jet-frozen vitrified material have been investigated. A structural difference between vitrified liquid water and amorphous solid water prepared from the vapour phase is inferred from a comparison of the X-ray diffraction patterns.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Olander, D. S. & Rice, S. A. Proc. natn. Acad. Sci. U.S.A. 69, 98–100 (1972).

    Article  ADS  CAS  Google Scholar 

  2. Rice, S. A. & Sceats, M. G. J. phys. Chem. 85, 1108–1119 (1981).

    Article  CAS  Google Scholar 

  3. Narten, A. H., Venkatesh, C. G. & Rice, S. A. J. chem. Phys. 64, 1106–1121 (1976).

    Article  ADS  CAS  Google Scholar 

  4. Rice, S. A. Topics curr. Chem. 60, 109–200 (1975).

    Article  CAS  Google Scholar 

  5. Angell, C. A. in Treatise on Water Vol. 7 (ed. Franks F.) (in the press).

  6. Angell, C. A., Shuppert, J. & Tucker, J. C. J. phys. Chem. 77, 3092–3099 (1973).

    Article  CAS  Google Scholar 

  7. Speedy, R. J. & Angell, C. A. J. chem. Phys. 65, 851–858 (1976).

    Article  ADS  CAS  Google Scholar 

  8. Angell, C. A. & Tucker, J. C. J. phys. Chem. 84, 268–272 (1980).

    Article  CAS  Google Scholar 

  9. Mazur, P. Science 168, 939–949 (1970).

    Article  ADS  CAS  Google Scholar 

  10. Wolstenholme, G. E. W. & O'Connor, M. The Frozen Cell (Churchill, London, 1970).

    Google Scholar 

  11. Becker, E. D. & Pimentel, G. C. J. chem. Phys. 25, 224–228 (1956).

    Article  ADS  CAS  Google Scholar 

  12. Fletcher, N. H. Rep. Prog. Phys. 34, 913–994 (1971).

    Article  ADS  CAS  Google Scholar 

  13. Pryde, J. A. & Jones, G. O. Nature 170, 685–688 (1952).

    Article  ADS  CAS  Google Scholar 

  14. Brüggeller, P. & Mayer, E. Nature 288, 569–571 (1980).

    Article  ADS  Google Scholar 

  15. Bachmann, L. & Schmitt, W. W. Proc. natn. Acad. Sci. U.S.A. 68, 2149–2152 (1971); in Freeze Etching (eds Benedetti, E. L. & Favard, P.) 73–79 (Soc. Frac. Microsc. Electron, Paris 1973).

    Google Scholar 

  16. Stewart, G. W. & Mannheimer, M. Z. anorg. allg. Chem. 171, 61–72 (1928).

    Article  CAS  Google Scholar 

  17. Sahores, J. J. Adv. X-ray Analysis 16, 186–197 (1973).

    Article  CAS  Google Scholar 

  18. Berry, P. F., Furuta, T. & Rhodes, J. R. Adv. X-ray Analysis 12, 612–632 (1969).

    CAS  Google Scholar 

  19. Berglund, R. N. & Lui, B. Y. H. Envir. Sci. Technol. 7, 147–153 (1973).

    Article  ADS  CAS  Google Scholar 

  20. Dowell, L. G. & Rinfret, A. P. Nature 188, 1144–1148 (1960).

    Article  ADS  CAS  Google Scholar 

  21. Uhlmann, D. R. J. Non-Cryst. Solids 7, 337–348 (1972).

    Article  ADS  CAS  Google Scholar 

  22. Hobbs, P. Ice Physics (Clarendon, Oxford, 1974).

    Google Scholar 

  23. Kauzmann, W. Chem. Rev. 43, 219–256 (1948).

    Article  CAS  Google Scholar 

  24. Rasmussen, D. H., MacKenzie, A. P., Tucker, J. C. & Angell, C. A. Science 181, 342–344 (1973).

    Article  ADS  CAS  Google Scholar 

  25. Kanno, H. & Angell, C. A. J. chem. Phys. 73, 1940–1947 (1980).

    Article  ADS  CAS  Google Scholar 

  26. Bruckner, R. J. Non-Cryst. Solids 5, 281 (1971).

    Article  ADS  Google Scholar 

  27. Rice, S. A., Bergren, M. S. & Swingle, L. Chem. Phys. Lett. 59, 14–16 (1978).

    Article  ADS  CAS  Google Scholar 

  28. Rice, S. A. & Sceats, M. G. J. phys. Chem. 85, 1108–1119 (1981).

    Article  CAS  Google Scholar 

  29. Johari, G. P. Phil. Mag. 35, 1077–1090 (1977).

    Article  ADS  CAS  Google Scholar 

  30. Narten, A. H. & Levy, H. A. J. chem. Phys. 55, 2263–2269 (1971).

    Article  ADS  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Mayer, E., Brüggeller, P. Vitrification of pure liquid water by high pressure jet freezing. Nature 298, 715–718 (1982). https://doi.org/10.1038/298715a0

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1038/298715a0

  • Springer Nature Limited

This article is cited by

Navigation