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Structure of Anomalous Water and Its Mechanism

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Abstract

SINCE the discovery of “anomalous water”1, several models2–12 have been proposed for its structure. I derive here a model based on present experimental knowledge, and then explain its mechanism.

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References

  1. Derjaguin, B. V., Churaev, N. V., Fedyakin, N. N., Talaev, M. V., and Ershova, I. G., Izv. Akad. Nauk SSSR, 10, 2178 (1967), and Bull. Acad. Sci. USSR, Div. Chem. Sci., 2095 (1967).

    Google Scholar 

  2. Bolander, R. W., Kassner, jun., J. L., and Zung, J. T., Nature, 221 1233 (1969).

    Article  ADS  CAS  Google Scholar 

  3. Bellamy, L. J., Osborn, A. R., Lippincott, E. R., and Bandy, A. R., Chem. Ind., 686 (1969).

  4. Lippincott, E. R., Stromberg, R. R., Grant, W. H., and Cessac, G. L., Science, 164, 1482 (1969).

    Article  ADS  CAS  Google Scholar 

  5. Donohue, J., Science, 166, 1000 (1969).

    Article  ADS  CAS  Google Scholar 

  6. Morokuma, K., Chem. Phys. Lett., 4, 358 (1969).

    Article  ADS  CAS  Google Scholar 

  7. Hertl, W., and Hair, M. L., Nature, 223, 1150 (1969).

    Article  ADS  CAS  Google Scholar 

  8. Petsko, G. A., Science, 167, 171 (1970).

    Article  ADS  CAS  Google Scholar 

  9. Allen, L. C., and Kollman, P. A., Science, 167, 1443 (1970).

    Article  ADS  CAS  Google Scholar 

  10. Erlander, S. R., Phys. Rev. Lett., 22, 177 (1969).

    Article  ADS  CAS  Google Scholar 

  11. Erlander, S. R., Phys. Rev. A., 1, 868 (1970).

    Article  ADS  CAS  Google Scholar 

  12. Linnett, J. W., Science, 167, 1720 (1970).

    Article  ADS  Google Scholar 

  13. Anway, A. R., J. Chem. Phys., 50, 2012 (1969).

    Article  ADS  CAS  Google Scholar 

  14. Robinson, R. A., and Harned, H. S., Chem. Rev., 28, 419 (1941).

    Article  CAS  Google Scholar 

  15. Perrin, D. D., J. Chem. Soc., 3189 (1960).

  16. Grunwald, E., and Fong, D.-W., J. Phys. Chem., 73, 650 (1969).

    Article  CAS  Google Scholar 

  17. Wall, T. T., and Hornig, D. F., J. Chem. Phys., 47, 784 (1967).

    Article  ADS  CAS  Google Scholar 

  18. Del Bene, J., and Pople, J. A., Chem. Phys. Lett., 4, 426 (1969).

    Article  ADS  CAS  Google Scholar 

  19. Nakamoto, K., Margoshes, M., and Rundle, R. E., J. Amer. Chem. Soc., 77, 6480 (1955).

    Article  CAS  Google Scholar 

  20. Derjaguin, B. V., and Churaev, N. V., Priroda, 16 (1968).

  21. Lamberts, L., and Huyskens, P., First Intern. Conf. Calorimetry and Thermodynamics, Warsaw, paper M8 (1969).

  22. Lamberts, L., J. Chim. Phys., 62, 1404 (1965).

    Article  CAS  Google Scholar 

  23. Neerinck, D., van Audenhaege, A., and Lamberts, L., Ann. Chim. (France), 4, 51 (1969).

    Google Scholar 

  24. Drost-Hansen, W., Ind. Eng. Chem., 61, 10 (1969).

    Article  CAS  Google Scholar 

  25. Frank, F. C., Nature, 157, 267 (1946).

    Article  ADS  CAS  Google Scholar 

  26. Baugham, D. H., Nature, 157, 733 (1946).

    Article  ADS  Google Scholar 

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CHUA, K. Structure of Anomalous Water and Its Mechanism. Nature 227, 834–836 (1970). https://doi.org/10.1038/227834b0

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  • DOI: https://doi.org/10.1038/227834b0

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