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Photodissociation of Nitroso Dimers

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Abstract

MOST C-nitroso compounds in the crystalline state exist as colourless dimers, though the monomers, often formed by dissociation in solution, are green or blue1–3. Heating solutions of the nitroso compounds also shifts the equilibrium so that formation of monomers is enhanced.

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References

  1. Ingold, C. K., and Piggott, H. A., J. Chem. Soc., 125, 169 (1924).

    Google Scholar 

  2. Hammick, D. L., J. Chem. Soc., 3105 (1931).

    Article  CAS  Google Scholar 

  3. Luttke, W., and Gowenlock, B. G., Quart. Rev. (London), 12, 321 (1958).

    Article  Google Scholar 

  4. Aston, J. G., Menard, D. F., and Mayberry, M. G., J. Amer. Chem. Soc., 54, 1530 (1932).

    Article  CAS  Google Scholar 

  5. Muller, E., Metzger, H., and Fries, D., Chem. Ber., 87, 1449 (1954); Jander, J., and Haszeldine, R. N., J. Chem. Soc., 912 (1954), and reference 12.

    Article  CAS  Google Scholar 

  6. Rao, C. N. R., in Chemical Applications of Infrared Spectroscopy, 271 (Academic Press, New York, 1963).

    Google Scholar 

  7. Piloty, O., and Steinbock, H., Chem. Ber., 35, 3101 (1902).

    Article  CAS  Google Scholar 

  8. Maruyamo, K., Tanikaga, R., and Goto, R., Bull. Chem. Soc. Japan, 37, 1893 (1964).

    Article  Google Scholar 

  9. Strom, E. T., and Bluhm, A. L., Chem. Commun., 115 (1966).

  10. Mackor, A., Wajer, Th. A. J. W., de Boer, Th. J., and van Voorst, J. D. W., Tetrahedron Lett., 2115 (1966).

  11. Schwartz, J. R., J. Amer. Chem. Soc., 79, 4353 (1957).

    Article  CAS  Google Scholar 

  12. Anderson, K. D., and Hammick, D. L., J. Chem. Soc., 30 (1935).

  13. Batt, L., and Gowenlock, B. G., J. Chem. Soc., 376 (1960).

  14. Gowenlock, B. G., and Kay, J., J. Chem. Soc., 3880 (1962).

  15. Keussler, V., and Luttke, W., Z. Elektrochem., 63, 614 (1959).

    CAS  Google Scholar 

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BLUHM, A., WEINSTEIN, J. Photodissociation of Nitroso Dimers. Nature 215, 1478–1479 (1967). https://doi.org/10.1038/2151478a0

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  • DOI: https://doi.org/10.1038/2151478a0

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