Abstract
AT suitably activated palladium cathodes, the diffusion or hydride component of hydrogen Overpotential η2 (or ηd) can be separated conveniently from the total apparent Overpotential, η, by extrapolation of plots against time of changes in the open circuit potential, E, measured after cessation of electrolysis1–3.
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Clamroth, R., and Knorr, C. A., Z. Elektrochem., 57, 399 (1953).
Barton, J. C., and Lewis, F. A., Z. Physik. Chem. Neue Folge, 33, 99 (1962).
Green, J. A. S., and Lewis, F. A., Trans. Faraday Soc., 60, 2234 (1964).
Kandler, L., Knorr, C. A., and Schwitzer, C., Z. Physik. Chem. Lpz., A, 180, 281 (1937).
Fallon, R. J., and Castellan, G. W., J. Phys. Chem., 64, 4 (1960).
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HULL, M., LEWIS, F. Diffusion or Hydride Component of Hydrogen Overpotential at Platinized Platinum and Palladized Palladium Cathodes. Nature 208, 887–888 (1965). https://doi.org/10.1038/208887a0
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DOI: https://doi.org/10.1038/208887a0
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