Skip to main content
SpringerLink
Log in

Formation of Rh(I)-Carbonyl Complex by the Reaction with Some Non-alcoholic, Oxygen-containing Solvents

  • Letter
  • Published:

From Nature

View current issue Submit your manuscript

    We’re sorry, something doesn't seem to be working properly.

    Please try refreshing the page. If that doesn't work, please contact support so we can address the problem.

Abstract

IT has been shown1,2 from an examination of the polarographic behaviour of some Rh(III)-arsine and phosphine complexes in dimethylformamide (DMF) as solvent that these complexes undergo reaction with the solvent. To elucidate this reaction and to identify the reaction product, an investigation has been undertaken, the results of which are reported here.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Rusina, A., Ph.D. thesis, Polarographic Institute, Prague (1965).

  2. Rusina, A., and VIček, A. A., Proc. Symp. Structure and Properties of Coordination Compounds, 65 (Bratislava, September 1964).

  3. Vallarino, L., J. Chem., 2287 (1957).

  4. Chatt, J., and Shaw, B. L., Chem. and Indusl., 290 (1961).

  5. Vaska, L., Chem. and Indust., 1402 (1961).

  6. Vaska, L., and Di Luzio, J. W., J. Amer. Chem. Soc., 83, 2784 (1961).

    Article  CAS  Google Scholar 

  7. Vaska, L., J. Chem., 83, 756 (1961).

    CAS  Google Scholar 

  8. Shaw, B. L., and Chatt, J., Proc. Seventh ICCC, 293, Stockholm (1962).

Download references

Author information

Authors and Affiliations

  1. J. Heyrovsky's Polarographic Institute, Czechoslovak Academy of Sciences, Prague

    A. RUSINA & A. A. VLČEK

Authors
  1. A. RUSINA
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. A. VLČEK
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

RUSINA, A., VLČEK, A. Formation of Rh(I)-Carbonyl Complex by the Reaction with Some Non-alcoholic, Oxygen-containing Solvents. Nature 206, 295–296 (1965). https://doi.org/10.1038/206295a0

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1038/206295a0

  • Springer Nature Limited

This article is cited by

Search

Navigation