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Production of Gallium by Continuous Electrodeposition from Acidic Solutions

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Abstract

As a means of production, electrolysis of gallium from only alkaline and not acidic solutions has been reported1. The principal difficulties reported using acidic solutions are: (a) poor current efficiencies; (b) formation of solid gallium oxychloride2.

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References

  1. Hampel, C. A., Rare Metals Handbook, sec. ed., 185 (Reinhold Publishing Corp., New York, 1961).

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  2. Papp, E., and Solymar, K., Acta Chim. Hung., 24, 451 (1960).

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  3. Hutter, J. C., and Peyron, A., C.R. Congr. intern. Chim. Ind., 31e, Liège, 1958 (publ. as Indust. Chim. belge, Supp.), 1, 801 (1959).

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  4. Saltman, W. M., and Nachtrieb, N. H., J. Electrochem. Soc., 100, 126 (1953).

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  5. Information on Gallium (Inform. Bull)., Aluminium-Industrie-Aktien-Gesellschaft, Neuhausen am Rheinfall/Switzerland (1956).

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STEARNS, R. Production of Gallium by Continuous Electrodeposition from Acidic Solutions. Nature 203, 749–750 (1964). https://doi.org/10.1038/203749b0

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