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Ligand Field for Chromic Ions in the Corundum Lattice

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Abstract

RECENT work on absorption spectra and lattice spacings in the Al2O3–Cr2O3 solid solution1–6 has been in sufficient agreement to warrant a fitting of the optical results to the crystal field-splitting diagram7. The relevant terms are shown in Fig. 1, which also shows the transitions involved in the yellow and blue absorption bands.

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References

  1. Graham, J., J. Phys. Chem. Solids, 17 (1/2), 18 (1960).

    Article  ADS  CAS  Google Scholar 

  2. Schultz, G., Conf. Physics and Chemistry of Crystal Phosphors (Greifswald, 1959), 219 (Akademie-Verlag, Berlin, 1960).

    Google Scholar 

  3. Schmitz-Dumont, O., and Reinen, D., Z. Elektrochem., 68 (8), 978 (1959).

    Google Scholar 

  4. Mandarino, J. A., Amer. Mineralogist, 44 (9/10); 961 (1959).

    CAS  Google Scholar 

  5. Jan, J. P., Steinemann, S., and Dinichert, P., Helv. Phys. Acta, 33 (2), 123 (1960).

    CAS  Google Scholar 

  6. Neuhaus, A., Z. Krist., 113, 195 (1960) (includes spectra by W. Schilly).

    Article  CAS  Google Scholar 

  7. Tanabe, Y., and Sugano, S., J. Phys. Soc., Japan, 9, 766 (1954).

    Article  ADS  CAS  Google Scholar 

  8. Tsuchida, R., see ref. 6, 775.

  9. Schäffer, C. E., and Jorgensen, C. K., J. Inorg. Nuclear Chem., 8, 143 (1958).

    Article  Google Scholar 

  10. Dunn, T. M., J. Chem. Soc., (2) 623 (1959).

  11. Schultz, G., Annalen der Phys., 6 (7/8), 345 (1960).

    Article  ADS  Google Scholar 

  12. Goodenough, J. B., J. App. Phys., 31, 3595 (1960).

    Google Scholar 

  13. Schäffer, C. E., J. Inorg. Nuclear Chem., 8, 149 (1958).

    Article  Google Scholar 

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GRAHAM, J., SCAIFE, D. Ligand Field for Chromic Ions in the Corundum Lattice. Nature 192, 161–163 (1961). https://doi.org/10.1038/192161b0

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