Skip to main content
Log in

Compressibility and Specific Evaporation Resistance of the Monolayers of Long-Chain Alcohols and Glycol Monoalkyl Ethers

  • Letter
  • Published:

From Nature

View current issue Submit your manuscript

Abstract

THE monolayers of long-chain compounds such as cetyl and stearyl alcohols are being used extensively to minimize the loss of water by evaporation in reserviors1. Permeability of water vapour through a monolayer depends on, among others, the magnitude of the van der Waals type of cohesive forces of the film molecule with its neighbours, and on the adhesive force between the monolayer and the water subphase. Further extension of the n-alkyl chain and/or suitable modification of the terminal polar group would, therefore, make a monolayer more effective in reducing evaporation.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. a, Mansfield, W. W., Nature, 175, 247 (1955). b, Mansfield, W. W., 172, 1101 (1953). c, Mansfield, W. W., Austral. J. App. Sci., 9 (3), 245 (1958).

    Article  ADS  Google Scholar 

  2. a, Deo, A. V., et al., Nature, 187, 870 (1960). b, Kulkarni, S. B., et al., (i) Ind. Pat. No. 70670 (1960); (ii) Australian Pat. No. 63866 (1960) and also U.S. Patent No. 62522 (1960).

    Article  ADS  CAS  Google Scholar 

  3. Cary, A., and Rideal, E. K., Proc. Roy. Soc., A, 109, 318 (1925).

    Article  ADS  CAS  Google Scholar 

  4. Nutting, G. C., and Harkins, W. D., J. Amer. Chem. Soc., 61, 1180 (1939).

    Article  CAS  Google Scholar 

  5. a, Langmuir, I., and Schaefer, V. J., J. Franklin Inst., 235, 119 (1943). b, Archer, R. J., and La Mer, V. K., J. Phys. Chem., 59, 200 (1955).

    Article  CAS  Google Scholar 

  6. La Mer, V. K., and Barnes, G. T., Proc. U.S. Nat. Acad. Sci., 45 (8), 1274 (1959).

    Article  ADS  CAS  Google Scholar 

  7. Rosano, H. L., and La Mer, V. K., J. Phys. Chem., 60, 348 (1956).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

DEO, A., KULKARNI, S., GHARPUREY, M. et al. Compressibility and Specific Evaporation Resistance of the Monolayers of Long-Chain Alcohols and Glycol Monoalkyl Ethers. Nature 191, 378–379 (1961). https://doi.org/10.1038/191378a0

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1038/191378a0

  • Springer Nature Limited

Navigation