Abstract
THIS reaction1 has been reinvestigated using a reaction tube containing a second short filament adjacent to the catalyst filament, so that adsorbed films on the latter might be detected by a measurement of their contact potential2. In this way it was shown that the filament in its most catalytically active state was free from adsorbed oxygen. Under these conditions, as J. K. Roberts3 has pointed out, the clean wire on exposure to gaseous H2 takes up a stable film of hydrogen, which does not evaporate appreciably at room temperature, and so cannot give a para H2 conversion by the mechanism suggested by Farkas1, namely by H2+2W ⇄ 2WH (where W indicates a surface atom of tungsten). It is, however, possible4 that the conversion might occur by a surface interchange reaction of the type pH2 + WH → 0H2+ HW, and this mechanism gains support from the following experiment.
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References
Farkas, A., Z. physikal. Chemie, B, 14, 371 (1931).
Bosworth, R. C. L., and Rideal, E. K., Proc. Roy. Soc., A, 162, 1 (1937); Bosworth, R. C. L., Proc. Camb. Phil. Soc., 33, 394 (1937).
Roberts, J. K., Trans. Faraday Soc., 35, 941 (1939).
Rideal, E. K., Proc. Camb. Phil. Soc., 35, 130 (1939).
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ELEY, D., RIDEAL, E. Parahydrogen Conversion on Tungsten. Nature 146, 401–402 (1940). https://doi.org/10.1038/146401d0
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DOI: https://doi.org/10.1038/146401d0
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