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Surface Active Substances (SAS) and Dissolved Organic Matter (DOC) in Atmospheric Precipitation of Urban Area of Croatia (ZAGREB)

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Abstract

We report measurements of surface active substances (SAS) in atmospheric bulk precipitation on the basis of adsorption characteristics on the mercury electrode by using phase sensitive alternating current voltammetry (out-of-phase measurement). Samples collected during the 1998–1999 at an urban area of Croatia. The obtained surfactant activity values were within the range of 0.09–0.37 mg dm−3 eq. Triton X-100. Concentrations of dissolved organic carbon (DOC) in the same samples were in the range of 0.78–4.39 mg dm−3. In this paper, we also used Pb2+ ion as an electrochemical probe for additional characterization of the properties of the organic matter in precipitation, which may be important in various atmospheric processes.

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References

  • Atlas, E. and Giam, C. S.: 1988, ' Ambient concentration and precipitation scavenging of atmospheric organic pollutants', Wat. Air Soil Poll. 38, 19–36.

    Google Scholar 

  • Bají c, A.: 1999, ' Airborne pollution transportation in the Dubrovnik Region', in Proceedings of 2nd Croation Conference on Waters, Dubrovnik, Croatia, 19-22 May 1999, pp. 137–143.

  • Bidleman, T. F., Billings, W. N. and Foreman, W. T.: 1986, 'Vapour-particle partitioning of semivolatile organic compounds: estimates from field collections', Environ. Sci. Technol. 20, 1038–104

    Google Scholar 

  • Brorstrom-Lunden, E.: 1996, ' Atmospheric deposition of persistent organic compounds to the sea surface', J. Sea Res. 35, 81–90.

    Google Scholar 

  • Brun, G. L., Howell, G. D. and O'Neill, H. J.: 1991, 'Spatial and temporal patterns of organic contaminants in wet precipitation in Atlantic Canada', Environ. Sci. Technol. 25, 1249–1261.

    Google Scholar 

  • Buffle, J.: 1988, Complexation Reactions in Aquatic Systems, Ellis Horwood, Chichester.

    Google Scholar 

  • Capel, P. D., Gunde, R., Zurcher, F. and Giger, W.: 1990, 'Carbon speciation and surface tension of fog', Environ. Sci. Technol. 24, 722–727.

    Google Scholar 

  • Chebbi, A. and Carlie, P.: 1996, 'Carboxylic acid in the troposphere, occurrence, source, and sinks: a review', Atmos. Environ. 30, 4233–4249.

    Google Scholar 

  • Czuczwa, J., Leuenberger, C. and Giger, W.: 1988, 'Seasonal and temporal changes of organic com-pounds in rain and snow', Atmos. Environ. 22, 907–916

    Google Scholar 

  • Ćosović, B. and Vojvodić, V.: 1982, 'The application of a.c. polarography to the determination of surface active substances in seawater', Limnol. Oceanogr. 27, 361–369.

    Google Scholar 

  • Ćosović, B., Vojvodić, V. and Pleše, T.: 1985, 'Electrochemical determination and characterization of surface active substances in freshwater', Wat. Res. 19, 175–183.

    Google Scholar 

  • Ćosović, B. and Vojvodić, V.: 1987, 'Direct determination of surface active substances in natural waters', Mar. Chem. 22, 363–373.

    Google Scholar 

  • Ćosović, B. and Vojvodić, V.: 1989, 'Adsorption behaviour of the hydrophobic fraction of organic matter in natural waters', Mar. Chem. 28, 183–1

    Google Scholar 

  • Ćosović, B. and Vojvodić, V.: 1998, 'Voltammetric analysis of surface active substances in natural seawater', Electroanalysis 10, 429–434.

    Google Scholar 

  • Dickhut, R. M. and Gustafson, K. E.: 1995, 'Atmospheric input of selected polycyclic aromatic hydrocarbons and polychlorinated biphenyls to southern Chesapeake Bay', Mar. Poll. Bull. 30, 385–396.

    Google Scholar 

  • Franz, T. P. and Eisenreich, S. E.: 1993, 'Wet deposition of polychlorinated biphenyls to Green Bay, Lake Michigan', Chemosphere 26, 1767–1788.

    Google Scholar 

  • Franz, T. P.: 1994, 'Deposition of semivolatile organic chemical by snow', Ph.D. thesis, University of Minnesota, Minneapolis, MN.

    Google Scholar 

  • Gamble, D. S., Schnitzer, H., Kerndroff, H. and Langford, C. H.: 1983, 'Multi metal ion exchange equilibria with humic acid', Geochim. Cosmochim. Acta 47, 1311–1323.

    Google Scholar 

  • Gašparovíc, B. and Ćosović, B.: 1995, 'Reduction of o-nitrophenol as a tool for the rough character-ization of organic matter in seawater samples', Electroanalysis 7, 1136–1142.

    Google Scholar 

  • Gevao, B., Hamilton-Taylor, J. and Jones, K. C.: 1998, 'Polychlorinated biphenyl and polycyclic aromatic hydrocarbon deposition to and exchange at the air-water interface of Eshwaite Water, a small lake in Cumbria, UK', Environ. Poll. 102, 63–75.

    Google Scholar 

  • Golomb, D., Ryan, D., Underhill, J., Wade. T. and Zemba, S.: 1997, 'Atmospheric deposition of toxics onto Massachusetts Bay-II. Polycyclic aromatic hydrocarbons', Atmos. Environ. 31, 1361–1368.

    Google Scholar 

  • Gregor, D. J., Teixeira, C. F. and Rowsell, R.: 1996, 'Deposition of atmospherically transported polychlorinated biphenyls in the Canadian Artic', Chemosphere 33, 227–244.

    Google Scholar 

  • Grollert, C. Kasper, A. and Puxbaum, H.: 1997, 'Organic compounds in high alpine snow', Intern. J. Environ. Anal. Chem. 67, 213–222.

    Google Scholar 

  • Hedges, J. Y. and Lee, C. (Guest Editors): 1993, 'Measurement of dissolved organic carbon and nitrogen in natural waters', Mar. Che m. 41(1–3) (Special issue).

  • Kawamura, K. and Kaplan, I. R.: 1991, 'Organic compounds in rainwater', in L. D. Hansen and D. J. Eatough (eds.), Organic Chemistry of the Atmosphere, CRC Press, Boca raton, FL, USA, pp. 233–284.

    Google Scholar 

  • Kawamura, K., Steinberg, S. and Kaplan, I. R.: 1996, 'Concentracions of monocarboxylic and di-carboxylic acids and aldehydes in Southern California wet precipitations: Comparasion of urban and nonurban samples and compositional changes during scavenging', Atmos. Environ. 30, 1035–1052.

    Google Scholar 

  • Kesselmeier, J.: 2001, 'Exchange of short-chain oxygenated volatile organic compounds (VOCs) between plants and atmosphere: a compilation of field and laboratory studies', J. Atmos. Chem. 39, 219–233.

    Google Scholar 

  • Khare, P., Satsangi, G. S., Kumar, N., Kumari, K. M. and Srivastava, S. S.: 1997, 'HCHO, HCOOH and CH3COOH in air and rain water at a rural tropical site in North Central India', Atmos. Environ. 31, 3867–3875.

    Google Scholar 

  • Kozarac, Z., ¡ Zutí c, V. and Ćosović c, B.: 1976, 'Direct determination of nonionic and anionic detergents in effluents', Tenside Detergents 13, 260–265.

    Google Scholar 

  • Kozarac, Z., Nikolí c, S., Ru¡ zí c, I. and Ćosović c, B.: 1982, 'Inhibition of the electrode reaction in the presence of surfactants studied by differential pulse polarography. Cadmium(II) in sea water in the presence of Triton X-100', J. Electroanal. Chem. 137, 279–292.

    Google Scholar 

  • Kozarac, Z., Ćosović c, B. and Vojvodí c, V.: 1986, 'Effectc of natural and synthetic surface active substances on the electrochemical reduction of cadmium in neutral waters', Wat. Res. 20, 295–300.

    Google Scholar 

  • Kumar, N., Kulshrestha, U. C., Saxen, A., Kumari, K. M. and Srivastava, S. S.: 1993, 'Formate and acetate in monsoon rainwatero of Agra, India', J. Geohys. Res. 98, 5135–5137.

    Google Scholar 

  • Leister, D. L. and Baker, J. E.: 1994, 'Atmospheric deposition of organic contaminant contaminants to the Cheaspeake Bay', Atmos. Environ. 28, 1499–1520.

    Google Scholar 

  • Lindberg, S. E.: 1982, 'Factor influencing trace metals, sulfate and hydrogen ion concentrations in rain', Atmos. Environ. 16, 1701–1709.

    Google Scholar 

  • Ligocki, M. P., Leuenberger, C. and Pankow, J. F.: 1985, 'Trace organic compounds in rain-III. Particle scavenging of neutral organic compounds', Atmos. Environ. 19, 1619–1626.

    Google Scholar 

  • Likens, G. E., Edgerton, E. S. and Galloway, J. N.: 1983, 'The composition and deposition of organic carbon in precipitation', Tellus 35B, 16–24.

    Google Scholar 

  • Meyers, P. A. and Hites, R. A.: 1982, 'Extractable organic compounds in midwest rain and snow', Atmos. Environ. 16, 2169–2175.

    Google Scholar 

  • Nguyen, V. D. Merks, A. G. A. and Valenta, P.: 1990, 'Atmospheric deposition of acid, heavy metals, dissolved organic carbon and nutrients in the Datch Delta area in 1980-1986', Sci. Total Environ. 99, 77–91.

    Google Scholar 

  • Orloví c Leko, P.: 2001, 'Physico-chemical interactions of surface active substances with lead in the aquatic systems', Ph.D. thesis, University of Zagreb, Croatia, p. 114.

    Google Scholar 

  • Plavší, M., Ćosović, B. and Miletić, S.: 1991, 'Comparision of behaviour of copper, cadmium and lead in the presence of humic acid in sodium chloride solutions', Anal. Ghem. Acta 255, 15–21.

    Google Scholar 

  • Plavší, M. and Ćosović, B.: 1994, 'Influence of surface-active substances on the redox processes of metal ions: Contribution to the speciation analysis of metals in aquatic sysrems', Anal. Chim. Acta 284, 539–545.

    Google Scholar 

  • Reynolds, B. Fowler, D. and Thomas, S.: 1996, 'Chemistry of cloud water at an upland site in mid-Wales', Sci. Total. Environ. 188, 115–125.

    Google Scholar 

  • Sanusi, A., Wortham, H., Millet, M. and Mirabel, P.: 1996, 'Chemical composition of rainwater in eastern France', Atmos. Environ. 30, 59–71.

    Google Scholar 

  • Schnoor, J. L.: 1996, Environmental Modeling', John Wiley, New York, pp. 531–603.

    Google Scholar 

  • Sempere, R. and Kawamura, K.: 1994, 'Comparative distributions of dicarboxylic acids and related polar compounds in snow, rain and aerosols from urban atmosphere', Atmos. Environ. 28, 449–459.

    Google Scholar 

  • Sempere, R. and Kawamura, K.: 1996, 'Low molecular weight dicarboxylacid and related polar compounds in the remote marine rain samples collected from western Pacific', Atmos. Environ. 30, 1609–1619.

    Google Scholar 

  • Skeffington, R. A.: 1984, 'The chemistry of bulk precipitation at a site in southeast England-I. Small-scale spatial variation, frequency distributions and variation with time', Atmos. Environ. 18, 1683–1693.

    Google Scholar 

  • Sodergren, A.: 1987, 'Origin and composition of surface slicks in lakes of differing trophic status', Limnol. Oceanogr. 32, 1307–1316.

    Google Scholar 

  • Vojvodí c, V., Ćosović c, B. and Mirí c, V.: 1994, 'Fractionation of surface active substances on the XAD-8 resin. Part I. Mixture of model substances', Anal. Chim. Acta 295, 73–83.

    Google Scholar 

  • Valenta, P., Nguyen, V. D., Wagner, F. and Nurnberg, H. W.: 1986, 'The distribution of acid deposition in Germany', Experientia 42, 330–339.

    Google Scholar 

  • Wania, F., Hoff, F. J. T., Jia, C. Q. and Mackav, D.: 1998, 'The effects of snow and ice on the environmental behavior of hydrophobic organic chemicals', Environ. Poll. 102, 25–41.

    Google Scholar 

  • Yamasaki, H., Kuwata, K. and Miyamoto, H.: 1982, 'Effects of ambient temperature on aspects of airborne polycyclic aromatic hydrocarbons', Environ. Sci. Technol. 16, 189–194.

    Google Scholar 

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Correspondence to Z. Kozarac.

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Leko, P.O., Kozarac, Z. & Ćosović, B. Surface Active Substances (SAS) and Dissolved Organic Matter (DOC) in Atmospheric Precipitation of Urban Area of Croatia (ZAGREB). Water, Air, & Soil Pollution 158, 295–310 (2004). https://doi.org/10.1023/B:WATE.0000044855.60714.98

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