Abstract
Supported nano-gold catalysts have attracted rapidly growing interest due to their potential applicability to various reactions of industrial and environmental significance. In this article, we focus on the advances related to the direct vapor-phase oxidation of propene to propene oxide in the presence of molecular oxygen and hydrogen over gold catalysts supported on Ti-incorporated silica materials prepared by different methods. The importance of catalyst preparation and pretreatment method, nature of support material, Au particle size and loading amount is emphasized. Possibilities to enhance the catalyst performance by using promoters and by silylation are also discussed.
Similar content being viewed by others
References
B. Hammer and J.K. Norskov, Nature 376 (1995) 238.
M. Haruta, N. Yamada, T. Kobayashi and S. Iijima, J. Catal. 115 (1989) 301.
M. Haruta, S. Tsubota, T. Kobayashi, H. Kageyama, M.J. Genet and B. Delmon, J. Catal. 144 (1993) 175.
S.J. Ainsworth, Chem. Eng. News (1992) 9;M. McCoy, Chem. Eng. News (2001) 19.
K. Murata and Y. Koyozumi, Chem. Commun. (2001) 1356.
H. Orzesek, R.P. Schulz, U. Dingerdisses and W.E. Maier, Chem. Eng. Technol. 22 (1999) 8.
M.G. Clerici, G. Bellusi and U. Romano, J. Catal. 129 (1991) 159.
B. Notari, Catal. Today 18 (1993) 163.
E. Occhiello, Chem. Ind. 761 (1997) 19.
A. Sato, T. Miyake and T. Saito, Shokubai (Catalysts) 34 (1992) 132.
R. Meiers, U. Dingerdissen and W.F. Hölderich, J. Catal. 176 (1998) 376.
T. Hayashi, K. Tanaka and M. Haruta, J. Catal. 178 (1998) 566.
R.G. Bowman, H.W. Clark, J.J. Maj and G.E. Hartwell, PCT/US97/11414, PCT Pub. No. WO 98/00413, (1998).
T. Hayashi, M. Wada, M. Haruta and S. Tsubota, Jpn. Pat. Appl. No. H10-244156, PCT Pub. No. WO97/00869, US Patent 5,932,750, 1999).
A. Kuperman, R.G. Bowman, H.W. Clark, G.E. Hartwell, B.J. Schoeman, H.E. Tuinstra and G.R. Meima, US Patent 6,255,499, (2001).
T.A. Nijhuis, H. Huizinga, M. Makkee and J.A. Moulijn, Ind. Eng. Chem. Res. 38 (1999) 884.
E.E. Stangland, K.B. Stavens, R.P. Andres and W.N. Delgass, J.Catal. 191 (2000) 332.
G. Mul, A. Zwijnenburg, B. Linden, M. van der Makkee and J.A. Moulijn, J. Catal. 201 (2001) 128.
M. Haruta, Catalysis Surveys of Japan, 1 (1997) 61and references therein.
M. Haruta, Catal. Today 36 (1997) 123and references therein.
M. Haruta, Stud. Surf. Sci. Catal. 110 (1997) 123and references therein.
T. Hayashi, K. Tanaka and M. Haruta, Shokubai 37 (1995) 72.
Y.A. Kalvachev, T. Hayashi, K. Tanaka and M. Haruta, Stud. Surf. Sci. Catal. 110 (1997) 965.
M. Haruta, B.S. Uphade, S. Tsubota and A. Miyamoto, Res. Chem. Intermed. 24 (1998) 329.
B.S. Uphade, M. Okumura, S. Tsubota and M. Haruta, Appl. Catal. A: Gen. 190 (2000) 43.
B.S. Uphade, Y. Yamada, T. Akita, T. Nakamura and M. Haruta, Appl. Catal. A: Gen. 215 (2001) 137.
B.S. Uphade, T. Akita, T. Nakamura and M. Haruta, J. Catal. 209 (2002) 331.
A.K. Sinha, S. Seelan, T, Akita, S. Tsubota and M. Haruta, Appl. Catal. A: Gen. 240 (2003) 243.
A.K. Sinha, T. Akita, S. Tsubota and M. Haruta, Stud. Surf. Sci. Catal. [Eds: R. Aielloe E. Gaigneaux, D.E. De Vos, P. Grange, P.A. Jacobs, J.A. Martens, P. Ruis and G. Poncelet], 142 (2002) 611.
A.K. Sinha, S. Seelan, S. Tsubota and M. Haruta, Stud. Surf. Sci.Catal. E.M., R. Avello, F. Testa, and G.'Giordano [Eds: E.M. Gaigneaux, R. Avello, F. Testa and G. Giordano], 143 (2002) 167.
A.K. Sinha, S. Seelan, T. Akita, S. Tsubota and M. Haruta, Catal. Lett., (2003) 223.
M.P. Kapoor, A.K. Sinha, S. Seelan, S. Inagaki, S. Tsubota, H. Yoshida and M. Haruta, Chem. Commun. (2002) 2902.
C. Qi, T. Akita, M. Okumura and M. Haruta, Appl. Catal. 218 (2001) 81.
K.A. Davis, D.W. Goodman, J. Phys. Chem. B 104 (2000) 8557.
T. Akita, K. Tanaka, S. Tsubota, M. Haruta, J. Electron Microsc. 49 (2000) 657.
B.S. Uphade, S. Tsubota, T. Hayashi and M. Haruta, Chem. Lett. (1998) 1277.
S. Naito and M. Tanimoto, J. Chem. Soc. Chem. Commun. 12 (1988) 832.
A. Zwijnenburg, A. Goossens, W.G. Sloof, M.W.J. Crajé, A.M. van der Kraan, L. Jos de Jongh, M. Makkee and J.A Moulijn, J. Phys. Chem. B 106 (2002) 9853.
D. Bianchi, R. Bortolo, R. D'Aloisio and M. Ricci, Proc. 3rd Tokyo Conference on Advanced Catalytic Science and Technology, (TOCAT-3), Tokyo, Japan, (1998) p.434.
F. Boccuzzi, A. Chiorino, S. Tsubota and M. Haruta, J. Phys. Chem. 100 (1996) 3625.
P.P. Olivera, E.M. Patrito and H. Sellers, Surf. Sci. 313 (1994) 25.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Sinha, A., Seelan, S., Tsubota, S. et al. Catalysis by Gold Nanoparticles: Epoxidation of Propene. Topics in Catalysis 29, 95–102 (2004). https://doi.org/10.1023/B:TOCA.0000029791.69935.53
Issue Date:
DOI: https://doi.org/10.1023/B:TOCA.0000029791.69935.53