Skip to main content
SpringerLink
Log in

A new approach in the kinetic modelling of three-way catalytic reactions

  • Published:
Topics in Catalysis Aims and scope Submit manuscript

Abstract

Until now, the flexibility of a global kinetic approach in the modelling of three-way catalysis, for redox reactions, has met with little success. It is an approach, which is poorly adapted when considering all the physical and chemical phenomena involved in a catalytic cycle. To this end, the work presented herein describes a novel approach in the kinetic modelling which includes a comprehensive understanding of catalytic cycles. From this basis, we have established detailed reaction rate equations that successfully model three-way catalysts behaviour under different test reaction conditions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Kašpar J., Fornasiero P. and Graziani M. (1999). Catal. Today 50: 285

    Article  Google Scholar 

  2. K.C. Taylor, in: Catalysis Sciences and Technology, Vol. 5, eds J.R. Anderson and M. Boudard, (Springer Verlag, Berlin, 1984) p. 119.

  3. P. Granger, J.J. Lecomte, L. Leclercq and G. Lerclercq, Top. Catal. 16/17 (2001) 349

    Google Scholar 

  4. Peden C.H.F., Goodman D.W., Blair D.S., Berlowitz P.J., Fisher G.B. and Oh S.H. (1988). J. Phys. Chem. 92: 1563

    Article  CAS  Google Scholar 

  5. Cant N.W., Hicks P.C. and Lennon B.S. (1978). J. Catal. 54: 372

    Article  CAS  Google Scholar 

  6. Oh S.H. and Eickel C.C. (1991). J. Catal. 128: 526

    Article  CAS  Google Scholar 

  7. Y.F. Yu Yao, J. Catal. 87 (1984) 152.

    Google Scholar 

  8. T. Bunluesin, H. Cordatos and R.J. Gorte, J. Catal. 157 (1995) 222.

    Google Scholar 

  9. Oh S.H. and Eickel C.C. (1988). J. Catal. 112: 543

    Article  CAS  Google Scholar 

  10. R.H. Nibbelke, M.A.J. Campman, J.H.B.J. Hoebink and G.B. Marin, J. Catal. 171 (1997) 358.

    Google Scholar 

  11. R.H. Nibbelke, A.J.L. Nievergeld, J.H.B.J. Hoebink and G.B. Marin, Appl. Catal. B 19 (1998) 245.

    Google Scholar 

  12. Hecker W.C. and Bell A.T. (1983). J. Catal. 84: 200

    Article  CAS  Google Scholar 

  13. F. Fajardie, J.F. Tempère, J.M. Manoli, O. Touret, G. Blanchard, and G. Djéga-Mariadassou, J. Catal. 179 (1998) 469.

    Google Scholar 

  14. G. Djéga-Mariadassou, F. Fajardie, J.F. Tempère, J.M. Manoli, O. Touret and G. Blanchard, J. Mol. Catal. A 161 (2000) 179.

    Google Scholar 

  15. Bera P., Patil K.C., Jayaram V., Subbanna G.N. and Hegde M.S. (2000). J. Catal. 196: 293

    Article  CAS  Google Scholar 

  16. L. Salin, C. Potvin, J.F. Tempère, M. Boudart, G. Djéga- Mariadassou, and J.M. Bart, Ind. Eng. Chem. Res. 37 (1998) 4531.

  17. Lakis R.E., Cai Y., Stenger J.H.G. and Lyman C.E. (1994). J. Catal. 154: 276

    Article  Google Scholar 

  18. R.W. Mc Cabe and C. Wong, J. Catal. 121 (1989) 422.

Download references

Author information

Authors and Affiliations

  1. Laboratoire de Réactivité de Surface, Université Pierre et Marie Curie, CNRS UMR 7609, Case 178, 4 Place Jussieu, 75252, Paris Cedex 05, France

    I. Manuel, C. Thomas & G. Djéga-Mariadassou

  2. PSA Peugeot Citroën, 18 Rue des fauvelles, 92250, La Garenne Colombes, France

    I. Manuel, H. Colas & N. Matthess

Authors
  1. I. Manuel
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. C. Thomas
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. H. Colas
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. N. Matthess
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. G. Djéga-Mariadassou
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Manuel, I., Thomas, C., Colas, H. et al. A new approach in the kinetic modelling of three-way catalytic reactions. Topics in Catalysis 30, 311–317 (2004). https://doi.org/10.1023/B:TOCA.0000029768.22036.88

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/B:TOCA.0000029768.22036.88

Keywords:

Search

Navigation