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Square-Planar Nickel(II) O,O′-Dialkyldithiophosphato Complexes with Triphenylphosphine of the Type [NiX(S2P{OR}2)(PPh3)] (X = Cl, Br, I and NCS)

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Abstract

A series of new [NiX(S2P{O-c-Hex}2)(PPh3)](X = Cl−, Br−, I− and NCS−)(1)–(4) and [Ni(NCS)(S2P{OR}2)(PPh3)][R =n-Pr (5), i-Pr (6)] complexes has been synthesized and characterized by elemental analyses, f.i.r., i.r., u.v.–vis., 1H-, 13C{1H}- and 31P{1H}-n.m.r. spectra, magnetochemical and conductivity measurements. A single crystal X-ray analysis of [Ni(NCS)(S2P{O-n-Pr}2)(PPh3)](5) reveals the molecular structure of the complex and confirms a square-planar geometry around the central atom of nickel with the NCS anion coordinated via the nitrogen atom.

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References

  1. S.E. Livinstone, in: G. Wilkinson, R.D. Gillard and J.A. McCleverty (Eds.), Comprehensive Coordination Chemistry, Vol. 2, Ligands, Pergamon Press, Oxford, England, 1987, p. 643.

    Google Scholar 

  2. L. Saconi, S. Bani and A. Bencini, in: G. Wilkinson, R.D. Gillard and J.A. McCleverty (Eds.), Comprehensive Coordination Chemistry, Vol. 5, Late Transition Elements, Pergamon Press, Oxford, 1987, p. 174.

    Google Scholar 

  3. S. Wingefors, Acta Chem. Scand. A, 34, 327 (1980).

    Google Scholar 

  4. K. Rüfenacht, Helv. Chim. Acta, 51, 518 (1968).

    Google Scholar 

  5. V.V. Mikhailov, Y.V. Kokhanov, K.S. Kazarian, E.N. Matveeva and A.A. Kozodoi, Plast. Massy, 9, 23 (1970).

    Google Scholar 

  6. H. So, Y.C. Lin, G.G.S. Huang and T.S.T. Chang, Wear, 166, 17 (1993).

    Google Scholar 

  7. J.A. McCleverty, S. Gill, R.S.Z. Kowalski, N.A. Bailey, H. Adams, K.W. Lumbard and M.A. Murphy, J. Chem. Soc., Dalton Trans., 493 (1982).

  8. H.E. Francis, G.L. Tincher, W.F. Wagner, J.R. Wasson and G.M. Woltermann, Inorg. Chem., 10, 2620 (1970).

    Google Scholar 

  9. S.E. Livingstone and A. E. Mihkelson, Inorg. Chem., 9, 2545 (1970).

    Google Scholar 

  10. C.P. Bhasin, R. Bohra, G. Srivastava, R.C. Mehrotra and P.B. Hitchcock, Inorg. Chim. Acta, 164, 11 (1989).

    Google Scholar 

  11. V. Machala, Z. Trávníček, Z. Šindelář, L. Kvítek and J. Marek, Transition Met. Chem., 25, 715 (2000).

    Google Scholar 

  12. N. Yoon, M.J. Incorvia and J.I. Zink, J. Chem. Soc., Chem. Comm., 499 (1972).

  13. S.-X. Liu, Ch.-Ch. Lin, Y.-P. Yu, D.-L. Zhu, Z. Xu, S.-H. Gou and X.-Z. You, Acta Crystallogr. C, 47, 43 (1991).

    Google Scholar 

  14. V. Machala, Z. Trávníček and J. Marek, Univ. Ostraviensis., Acta Fac. Rerum Nat., 8, 199 (2001).

    Google Scholar 

  15. L. Szüčová, Z. Trávníček and J. Marek, Polyhedron, 22, 1341 (2003).

    Google Scholar 

  16. G.M. Sheldrick, SHELXS-97, Acta Crystallogr. A, 46, 467 (1990).

    Google Scholar 

  17. G.M. Sheldrick, SHELXL-97, Program for Crystal Structure Refinement, University of Göttingen, Göttingen, Germany, 1997.

    Google Scholar 

  18. W.J. Geary, Coord. Chem. Rev., 7, 81 (1971).

    Google Scholar 

  19. A.B.P. Lever, Inorganic Electronic Spectroscopy, 2nd Edit., Elsevier, Amsterdam, 1984, p. 343.

    Google Scholar 

  20. K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, 5th Edit., Part B: Application in Coordination, Organometallic, and Bioinorganic Chemistry. Wiley, New York, 1997, p. 116, 184.

    Google Scholar 

  21. M.R.L. Oliveira, H.P. Vieira, G.J. Perpétuo, J. Janezak and V.M. De Bellis, Polyhedron, 21, 2243 (2002).

    Google Scholar 

  22. A.V. Ivanov, W. Forsling, M. Kritikos, O.N. Anzutkin, A.C. Larsson, F.A. Zhukov and Z.F. Yusupov, Doklady Chem., 375, 195 (2000).

    Google Scholar 

  23. T.S. Lobana, S. Paul, G. Hundal and S. Obrai, Transition Met. Chem., 24, 202 (1999).

    Google Scholar 

  24. R. Pastorek, J. Kameníček, Z. Trávníček, Z Šindelář, F. Březina and S. Sobancová, Acta Univ. Palacki. Olomuc., Fac. Rerum Nat., 117, 11 (1994).

    Google Scholar 

  25. R. Pastorek, J. Kameníček, F. Březina, Z. Šindelář, E. Jehlářová, N.V. Duffy and T. Glowiak, Chem. Papers, 48, 317 (1994).

    Google Scholar 

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Authors and Affiliations

  1. Department of Inorganic Chemistry, Palacký University, Křížkovského 10, CZ-771 47, Olomouc, Czech Republic

    Zdeněk Trávníček, Viktor Machala, Lucie Szüčová & Michal Maloň

  2. Laboratory of Functional Genomics and Proteomics, Masaryk University, Kotlářská 2, CZ-611 37, Brno, Czech Republic

    Jaromír Marek

Authors
  1. Zdeněk Trávníček
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  2. Viktor Machala
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  3. Lucie Szüčová
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  4. Michal Maloň
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  5. Jaromír Marek
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Trávníček, Z., Machala, V., Szüčová, L. et al. Square-Planar Nickel(II) O,O′-Dialkyldithiophosphato Complexes with Triphenylphosphine of the Type [NiX(S2P{OR}2)(PPh3)] (X = Cl, Br, I and NCS). Transition Metal Chemistry 29, 352–357 (2004). https://doi.org/10.1023/B:TMCH.0000027442.15747.34

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